N-acyl-5,5-dimethyl-oxazolidin-2-ones as latent aldehyde equivalents

Jordi Bach; Steven D. Bull; Stephen G. Davies; Rebecca L. Nicholson; Hitesh J. Sanganee; Andrew D. Smith

doi:10.1016/S0040-4039(99)01345-3

N-acyl-5,5-dimethyl-oxazolidin-2-ones as latent aldehyde equivalents

Jordi Bach^*, Steven D. Bull, Stephen G. Davies, Rebecca L. Nicholson, Hitesh J. Sanganee, Andrew D. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.

Original language	English
Pages (from-to)	6677-6680
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	36
DOIs	https://doi.org/10.1016/S0040-4039(99)01345-3
Publication status	Published - 3 Sept 1999

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title = "N-acyl-5,5-dimethyl-oxazolidin-2-ones as latent aldehyde equivalents",

abstract = "N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.",

author = "Jordi Bach and Bull, {Steven D.} and Davies, {Stephen G.} and Nicholson, {Rebecca L.} and Sanganee, {Hitesh J.} and Smith, {Andrew D.}",

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AU - Bach, Jordi

AU - Bull, Steven D.

AU - Davies, Stephen G.

AU - Nicholson, Rebecca L.

AU - Sanganee, Hitesh J.

AU - Smith, Andrew D.

PY - 1999/9/3

Y1 - 1999/9/3

N2 - N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.

AB - N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.

UR - http://www.scopus.com/inward/record.url?scp=0033520268&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(99)01345-3

DO - 10.1016/S0040-4039(99)01345-3

M3 - Article

AN - SCOPUS:0033520268

SN - 0040-4039

VL - 40

SP - 6677

EP - 6680

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 36

ER -

N-acyl-5,5-dimethyl-oxazolidin-2-ones as latent aldehyde equivalents

Abstract

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