N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction

John N. Low; Janet M. S. Skakle; Simon J. Garden; James L. Wardell; Christopher Glidewell

doi:10.1107/S0108270106020373

N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction

John N. Low, Janet M. S. Skakle, Simon J. Garden, James L. Wardell, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C13H8IN3O5, crystallizes with Z' = 2 in the space group P2(1)/n. The two independent molecules, which are both almost planar, are conformational isomers. The molecules are linked into complex sheets by a combination of five independent C-H center dot center dot center dot O hydrogen bonds and an almost linear two-centre iodo-nitro interaction.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	62
DOIs	https://doi.org/10.1107/S0108270106020373
Publication status	Published - Jul 2006

Keywords

PI-STACKING INTERACTIONS

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Low, J. N., Skakle, J. M. S., Garden, S. J., Wardell, J. L., & Glidewell, C. (2006). N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction. Acta Crystallographica Section C-Crystal Structure Communications, 62. https://doi.org/10.1107/S0108270106020373

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title = "N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction",

abstract = "The title compound, C13H8IN3O5, crystallizes with Z' = 2 in the space group P2(1)/n. The two independent molecules, which are both almost planar, are conformational isomers. The molecules are linked into complex sheets by a combination of five independent C-H center dot center dot center dot O hydrogen bonds and an almost linear two-centre iodo-nitro interaction.",

keywords = "PI-STACKING INTERACTIONS",

author = "Low, {John N.} and Skakle, {Janet M. S.} and Garden, {Simon J.} and Wardell, {James L.} and Christopher Glidewell",

year = "2006",

month = jul,

doi = "10.1107/S0108270106020373",

language = "English",

volume = "62",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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Low, JN, Skakle, JMS, Garden, SJ, Wardell, JL & Glidewell, C 2006, 'N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction', Acta Crystallographica Section C-Crystal Structure Communications, vol. 62. https://doi.org/10.1107/S0108270106020373

N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction. / Low, John N.; Skakle, Janet M. S.; Garden, Simon J. et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 62, 07.2006.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction

AU - Low, John N.

AU - Skakle, Janet M. S.

AU - Garden, Simon J.

AU - Wardell, James L.

AU - Glidewell, Christopher

PY - 2006/7

Y1 - 2006/7

N2 - The title compound, C13H8IN3O5, crystallizes with Z' = 2 in the space group P2(1)/n. The two independent molecules, which are both almost planar, are conformational isomers. The molecules are linked into complex sheets by a combination of five independent C-H center dot center dot center dot O hydrogen bonds and an almost linear two-centre iodo-nitro interaction.

AB - The title compound, C13H8IN3O5, crystallizes with Z' = 2 in the space group P2(1)/n. The two independent molecules, which are both almost planar, are conformational isomers. The molecules are linked into complex sheets by a combination of five independent C-H center dot center dot center dot O hydrogen bonds and an almost linear two-centre iodo-nitro interaction.

KW - PI-STACKING INTERACTIONS

U2 - 10.1107/S0108270106020373

DO - 10.1107/S0108270106020373

M3 - Article

SN - 1600-5759

VL - 62

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Low JN, Skakle JMS, Garden SJ, Wardell JL, Glidewell C. N-(2-hydroxy-3-iodo-5-nitrobenzyl-idene)-3-nitroaniline: conformational isomers linked into complex sheets by five C-H center dot center dot center dot O hydrogen bonds and a two-centre iodo-nitro interaction. Acta Crystallographica Section C-Crystal Structure Communications. 2006 Jul;62. doi: 10.1107/S0108270106020373