mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds

E M  Mohamed; K  Panchanatheswaran; J N  Low; C  Glidewell

doi:10.1107/S0108270104003981

mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds

E M Mohamed, K Panchanatheswaran, J N Low, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Sn2Cl4(C7H7)(4)(C26H24O2P2)], (I), was isolated from the reaction of 1,2-bis(diphenylphosphino)ethane with dibenzyltin(IV) dichloride in the presence of air. The molecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The molecules are linked into chains of rings by a single C-H...pi(arene) hydrogen bond.

Original language	English
Number of pages	2
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	60
DOIs	https://doi.org/10.1107/S0108270104003981
Publication status	Published - Apr 2004

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Mohamed, E. M., Panchanatheswaran, K., Low, J. N., & Glidewell, C. (2004). mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications, 60. https://doi.org/10.1107/S0108270104003981

Mohamed, E M ; Panchanatheswaran, K ; Low, J N et al. / mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds. In: Acta Crystallographica Section C-Crystal Structure Communications. 2004 ; Vol. 60.

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title = "mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds",

abstract = "The title compound, [Sn2Cl4(C7H7)(4)(C26H24O2P2)], (I), was isolated from the reaction of 1,2-bis(diphenylphosphino)ethane with dibenzyltin(IV) dichloride in the presence of air. The molecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The molecules are linked into chains of rings by a single C-H...pi(arene) hydrogen bond.",

author = "Mohamed, {E M} and K Panchanatheswaran and Low, {J N} and C Glidewell",

year = "2004",

month = apr,

doi = "10.1107/S0108270104003981",

language = "English",

volume = "60",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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Mohamed, EM, Panchanatheswaran, K, Low, JN & Glidewell, C 2004, 'mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds', Acta Crystallographica Section C-Crystal Structure Communications, vol. 60. https://doi.org/10.1107/S0108270104003981

mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds. / Mohamed, E M ; Panchanatheswaran, K ; Low, J N et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 60, 04.2004.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds

AU - Mohamed, E M

AU - Panchanatheswaran, K

AU - Low, J N

AU - Glidewell, C

PY - 2004/4

Y1 - 2004/4

N2 - The title compound, [Sn2Cl4(C7H7)(4)(C26H24O2P2)], (I), was isolated from the reaction of 1,2-bis(diphenylphosphino)ethane with dibenzyltin(IV) dichloride in the presence of air. The molecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The molecules are linked into chains of rings by a single C-H...pi(arene) hydrogen bond.

AB - The title compound, [Sn2Cl4(C7H7)(4)(C26H24O2P2)], (I), was isolated from the reaction of 1,2-bis(diphenylphosphino)ethane with dibenzyltin(IV) dichloride in the presence of air. The molecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The molecules are linked into chains of rings by a single C-H...pi(arene) hydrogen bond.

U2 - 10.1107/S0108270104003981

DO - 10.1107/S0108270104003981

M3 - Article

SN - 1600-5759

VL - 60

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Mohamed EM, Panchanatheswaran K, Low JN, Glidewell C. mu-Ethane-1,2-diylbis(diphenylphosphine oxide)-kappa O-2 : O '-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H center dot center dot center dot pi(arene) hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications. 2004 Apr;60. doi: 10.1107/S0108270104003981