Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand

Loïc Donato; Catherine McCusker; Felix Castellano; Eli Zysman-Colman

doi:10.1021/ic400478d

Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand

Loïc Donato, Catherine McCusker, Felix Castellano, Eli Zysman-Colman

Research output: Contribution to journal › Article › peer-review

Abstract

Mononuclear (1) and dinuclear (2) cationic iridium complexes incorporating a bridging 2,5-dipyridylpyrazine ligand have been synthesized and their optoelectronic properties are characterized. Whereas 1 emits in the deep red, 2 is photophysically inactive at 298 K though both luminesce at 77 K in a rigid matrix. The crystals structures for both complexes are also reported.

Original language	English
Pages (from-to)	8495–8504
Journal	Inorganic Chemistry
Volume	52
Issue number	15
Early online date	13 Jul 2013
DOIs	https://doi.org/10.1021/ic400478d
Publication status	Published - 5 Aug 2013

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title = "Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand",

abstract = "Mononuclear (1) and dinuclear (2) cationic iridium complexes incorporating a bridging 2,5-dipyridylpyrazine ligand have been synthesized and their optoelectronic properties are characterized. Whereas 1 emits in the deep red, 2 is photophysically inactive at 298 K though both luminesce at 77 K in a rigid matrix. The crystals structures for both complexes are also reported.",

author = "Lo{\"i}c Donato and Catherine McCusker and Felix Castellano and Eli Zysman-Colman",

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T1 - Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand

AU - Donato, Loïc

AU - McCusker, Catherine

AU - Castellano, Felix

AU - Zysman-Colman, Eli

PY - 2013/8/5

Y1 - 2013/8/5

N2 - Mononuclear (1) and dinuclear (2) cationic iridium complexes incorporating a bridging 2,5-dipyridylpyrazine ligand have been synthesized and their optoelectronic properties are characterized. Whereas 1 emits in the deep red, 2 is photophysically inactive at 298 K though both luminesce at 77 K in a rigid matrix. The crystals structures for both complexes are also reported.

AB - Mononuclear (1) and dinuclear (2) cationic iridium complexes incorporating a bridging 2,5-dipyridylpyrazine ligand have been synthesized and their optoelectronic properties are characterized. Whereas 1 emits in the deep red, 2 is photophysically inactive at 298 K though both luminesce at 77 K in a rigid matrix. The crystals structures for both complexes are also reported.

U2 - 10.1021/ic400478d

DO - 10.1021/ic400478d

M3 - Article

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VL - 52

SP - 8495

EP - 8504

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand

Abstract

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