Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

Ahmed M. Soliman; Mohammed Abdelhameed; Eli Zysman-Colman; Pierre D. Harvey

doi:10.1039/c3cc42634c

Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

Ahmed M. Soliman, Mohammed Abdelhameed, Eli Zysman-Colman, Pierre D. Harvey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C CPt(PBu3)(2)-C C), essentially no T-1[Ir] -> S-1/T-1[ZnTTP] energy transfer occurs.

Original language	English
Pages (from-to)	5544-5546
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	49
DOIs	https://doi.org/10.1039/c3cc42634c
Publication status	Published - 2013

Keywords

PLATINUM(II) ALKYNYL COMPLEXES
OPTICAL NLO PROPERTIES
SOLAR-CELLS
EXCITED-STATES
LUMINESCENCE
CHROMOPHORES
OLIGOMERS
PERFORMANCE
POLYMERS
LIGANDS

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10.1039/c3cc42634c

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@article{921171b5b23141358eda5c5471623e88,

title = "Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer",

abstract = "Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C CPt(PBu3)(2)-C C), essentially no T-1[Ir] -> S-1/T-1[ZnTTP] energy transfer occurs.",

keywords = "PLATINUM(II) ALKYNYL COMPLEXES, OPTICAL NLO PROPERTIES, SOLAR-CELLS, EXCITED-STATES, LUMINESCENCE, CHROMOPHORES, OLIGOMERS, PERFORMANCE, POLYMERS, LIGANDS",

author = "Soliman, {Ahmed M.} and Mohammed Abdelhameed and Eli Zysman-Colman and Harvey, {Pierre D.}",

year = "2013",

doi = "10.1039/c3cc42634c",

language = "English",

volume = "49",

pages = "5544--5546",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "49",

}

TY - JOUR

T1 - Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

AU - Soliman, Ahmed M.

AU - Abdelhameed, Mohammed

AU - Zysman-Colman, Eli

AU - Harvey, Pierre D.

PY - 2013

Y1 - 2013

N2 - Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C CPt(PBu3)(2)-C C), essentially no T-1[Ir] -> S-1/T-1[ZnTTP] energy transfer occurs.

AB - Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C CPt(PBu3)(2)-C C), essentially no T-1[Ir] -> S-1/T-1[ZnTTP] energy transfer occurs.

KW - PLATINUM(II) ALKYNYL COMPLEXES

KW - OPTICAL NLO PROPERTIES

KW - SOLAR-CELLS

KW - EXCITED-STATES

KW - LUMINESCENCE

KW - CHROMOPHORES

KW - OLIGOMERS

KW - PERFORMANCE

KW - POLYMERS

KW - LIGANDS

U2 - 10.1039/c3cc42634c

DO - 10.1039/c3cc42634c

M3 - Article

SN - 1359-7345

VL - 49

SP - 5544

EP - 5546

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Monitoring the on-off switching of the electronic communication in diethynylplatinum(II)-bridged dyads using triplet energy transfer

Abstract

Keywords

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