Model investigations for vanadium-protein interactions: first vanadium(III) complexes with dipeptides and their oxovanadium(IV) analogues

AJ Tasiopoulos, YG Deligiannakis, John Derek Woollins, Alexandra Martha Zoya Slawin, TA Kabanos

Research output: Other contribution

23 Citations (Scopus)

Abstract

Reaction of the dipeptides H(2)Gly-Tyr and H(2)Gly-Phe with VCl3 and 1,10-phenanthroline affords the compounds [V(Gly-Tyr)(phen)]Cl . 3MeOH 1 and [V(Gly-Phe)(phen)]Cl . 3MeOH 2; aerial oxidation of the complexes 1 and 2 gives their oxovanadium(Iv) analogues [VO(Gly-Tyr)(phen)] 3 and [VO(Gly-Phe(phen)] 4, respectively; the X-ray crystal structure of 3 is reported.

Original languageEnglish
Publication statusPublished - 7 Mar 1998

Keywords

  • CRYSTAL-STRUCTURE

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