Methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene and related ligands

A J  Rucklidge; G E  Morris; D J  Cole-Hamilton

doi:10.1039/b414460k

Methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene and related ligands

A J Rucklidge, G E Morris, D J Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

High selectivities to methyl acetoxypropanoate esters (b : l up to 3.6 : 1) are obtained from the methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene in the presence of acid, provided that the acid concentration does not exceed that of the free phosphine.

Original language	English
Pages (from-to)	1176-1178
Number of pages	3
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b414460k
Publication status	Published - 2005

Keywords

METHYL PROPANOATE
ETHENE
ESTERS

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10.1039/b414460k

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title = "Methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene and related ligands",

abstract = "High selectivities to methyl acetoxypropanoate esters (b : l up to 3.6 : 1) are obtained from the methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene in the presence of acid, provided that the acid concentration does not exceed that of the free phosphine.",

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year = "2005",

doi = "10.1039/b414460k",

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AU - Rucklidge, A J

AU - Morris, G E

AU - Cole-Hamilton, D J

PY - 2005

Y1 - 2005

N2 - High selectivities to methyl acetoxypropanoate esters (b : l up to 3.6 : 1) are obtained from the methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene in the presence of acid, provided that the acid concentration does not exceed that of the free phosphine.

AB - High selectivities to methyl acetoxypropanoate esters (b : l up to 3.6 : 1) are obtained from the methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene in the presence of acid, provided that the acid concentration does not exceed that of the free phosphine.

KW - METHYL PROPANOATE

KW - ETHENE

KW - ESTERS

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DO - 10.1039/b414460k

M3 - Article

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Methoxycarbonylation of vinyl acetate catalysed by palladium complexes of bis(ditertiarybutylphosphinomethyl) benzene and related ligands

Abstract

Keywords

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