Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst

Grant S. Forman; Ronan M. Bellabarba; Robert P. Tooze; Alexandra M. Z. Slawin; Ralf Karch; Roland Winde

doi:10.1016/j.jorganchem.2006.06.021

Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst

Grant S. Forman, Ronan M. Bellabarba, Robert P. Tooze, Alexandra M. Z. Slawin, Ralf Karch, Roland Winde

Research output: Contribution to journal › Article › peer-review

Abstract

The phoban-indenylidene complex is a robust catalyst for self-metathesis and ethenolysis reactions of methyl oleate. The phobanindenylidene catalyst was characterized by X-ray analysis, NMR and microanalysis and was used in various self-metathesis and ethenolysis of methyl oleate, giving rise to significantly higher end of run conversions compared to Grubbs 1st generation catalyst. These complexes are more stable and active than commercial Grubbs 1st generation catalyst, can be accessed from simple precursors and should give rise to more economical metathesis processes. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	5513-5516
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	691
DOIs	https://doi.org/10.1016/j.jorganchem.2006.06.021
Publication status	Published - 1 Dec 2006

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

metathesis
methyl oleate
renewable
green
fatty acid ester
Grubbs
carbene
ethenolysis
self-metathesis
RING-CLOSING METATHESIS
MEDIUM-SIZED RINGS
OLEFIN METATHESIS
ALLENYLIDENE COMPLEXES
GREEN CHEMISTRY
POLYMERIZATION
DECOMPOSITION
SYSTEM
OILS

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10.1016/j.jorganchem.2006.06.021

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@article{5a663fafe01a470895e1c94abb5cacd5,

title = "Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst",

abstract = "The phoban-indenylidene complex is a robust catalyst for self-metathesis and ethenolysis reactions of methyl oleate. The phobanindenylidene catalyst was characterized by X-ray analysis, NMR and microanalysis and was used in various self-metathesis and ethenolysis of methyl oleate, giving rise to significantly higher end of run conversions compared to Grubbs 1st generation catalyst. These complexes are more stable and active than commercial Grubbs 1st generation catalyst, can be accessed from simple precursors and should give rise to more economical metathesis processes. (c) 2006 Elsevier B.V. All rights reserved.",

keywords = "metathesis, methyl oleate, renewable, green, fatty acid ester, Grubbs, carbene, ethenolysis, self-metathesis, RING-CLOSING METATHESIS, MEDIUM-SIZED RINGS, OLEFIN METATHESIS, ALLENYLIDENE COMPLEXES, GREEN CHEMISTRY, POLYMERIZATION, DECOMPOSITION, SYSTEM, OILS",

author = "Forman, \{Grant S.\} and Bellabarba, \{Ronan M.\} and Tooze, \{Robert P.\} and Slawin, \{Alexandra M. Z.\} and Ralf Karch and Roland Winde",

year = "2006",

month = dec,

day = "1",

doi = "10.1016/j.jorganchem.2006.06.021",

language = "English",

volume = "691",

pages = "5513--5516",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst

AU - Forman, Grant S.

AU - Bellabarba, Ronan M.

AU - Tooze, Robert P.

AU - Slawin, Alexandra M. Z.

AU - Karch, Ralf

AU - Winde, Roland

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The phoban-indenylidene complex is a robust catalyst for self-metathesis and ethenolysis reactions of methyl oleate. The phobanindenylidene catalyst was characterized by X-ray analysis, NMR and microanalysis and was used in various self-metathesis and ethenolysis of methyl oleate, giving rise to significantly higher end of run conversions compared to Grubbs 1st generation catalyst. These complexes are more stable and active than commercial Grubbs 1st generation catalyst, can be accessed from simple precursors and should give rise to more economical metathesis processes. (c) 2006 Elsevier B.V. All rights reserved.

AB - The phoban-indenylidene complex is a robust catalyst for self-metathesis and ethenolysis reactions of methyl oleate. The phobanindenylidene catalyst was characterized by X-ray analysis, NMR and microanalysis and was used in various self-metathesis and ethenolysis of methyl oleate, giving rise to significantly higher end of run conversions compared to Grubbs 1st generation catalyst. These complexes are more stable and active than commercial Grubbs 1st generation catalyst, can be accessed from simple precursors and should give rise to more economical metathesis processes. (c) 2006 Elsevier B.V. All rights reserved.

KW - metathesis

KW - methyl oleate

KW - renewable

KW - green

KW - fatty acid ester

KW - Grubbs

KW - carbene

KW - ethenolysis

KW - self-metathesis

KW - RING-CLOSING METATHESIS

KW - MEDIUM-SIZED RINGS

KW - OLEFIN METATHESIS

KW - ALLENYLIDENE COMPLEXES

KW - GREEN CHEMISTRY

KW - POLYMERIZATION

KW - DECOMPOSITION

KW - SYSTEM

KW - OILS

UR - https://www.scopus.com/pages/publications/33751378204

U2 - 10.1016/j.jorganchem.2006.06.021

DO - 10.1016/j.jorganchem.2006.06.021

M3 - Article

SN - 0022-328X

VL - 691

SP - 5513

EP - 5516

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Metathesis of renewable unsaturated fatty acid esters catalysed by a phoban-indenylidene ruthenium catalyst

Abstract

UN SDGs

Keywords

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