METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

S  ANDERSON; A F  HILL; A M Z  SLAWIN; D J  WILLIAMS

METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

S ANDERSON, A F HILL, A M Z SLAWIN, D J WILLIAMS

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

Original language	English
Pages (from-to)	266-267
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	3
Publication status	Published - 7 Feb 1993

Keywords

COMPLEXES

Cite this

@article{b584ebdad7984b5d8ee191b31193666c,

title = "METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS",

abstract = "The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate",

keywords = "COMPLEXES",

author = "S ANDERSON and HILL, {A F} and SLAWIN, {A M Z} and WILLIAMS, {D J}",

year = "1993",

month = feb,

day = "7",

language = "English",

pages = "266--267",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "3",

}

TY - JOUR

T1 - METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

AU - ANDERSON, S

AU - HILL, A F

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

PY - 1993/2/7

Y1 - 1993/2/7

N2 - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

AB - The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

KW - COMPLEXES

M3 - Article

SN - 0022-4936

SP - 266

EP - 267

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 3

ER -

METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

Abstract

Keywords

Fingerprint

Cite this