METALLAOXETENE FORMATION BY COUPLING OF CARBAMOYL AND DIFLUOROCARBENE LIGANDS

S ANDERSON, A F HILL, A M Z SLAWIN, D J WILLIAMS

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The reaction of the carbamoyl complex [Fe{C(=O)NPri2}CF3(CO)2 (PPh3)] with potassium hydrotris(pyrazol-1-yl)borate provides the structurally characterised ferraoxetene [Fe{CF2OC(NPri2)}(CO){HB(pz)3}] (pz = pyrazol-1-yl), presumably via coupling of the carbamoyl ligand with a difluorocarbene intermediate

Original languageEnglish
Pages (from-to)266-267
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number3
Publication statusPublished - 7 Feb 1993

Keywords

  • COMPLEXES

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