Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

Lauren N. McHugh; Angela Terracina; Paul S. Wheatley; Gianpiero Buscarino; Martin  William Smith; Russell E. Morris

doi:10.1002/anie.201905779

Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

Lauren N. McHugh, Angela Terracina, Paul S. Wheatley, Gianpiero Buscarino, Martin William Smith, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of Toxic Industrial Chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.

Original language	English
Pages (from-to)	11747-11751
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	58
Issue number	34
Early online date	17 Jul 2019
DOIs	https://doi.org/10.1002/anie.201905779
Publication status	Published - 19 Aug 2019

Keywords

Porous materials
Metal-organic frameworks
Activated carbon
Gas adsorption
Water stability

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10.1002/anie.201905779

McHugh_2019_ACIE_MOFs_AAM
Copyright © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/anie.201905779
Accepted author manuscript, 1.51 MB

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title = "Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams",

abstract = "Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of Toxic Industrial Chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.",

keywords = "Porous materials, Metal-organic frameworks, Activated carbon, Gas adsorption, Water stability",

author = "McHugh, \{Lauren N.\} and Angela Terracina and Wheatley, \{Paul S.\} and Gianpiero Buscarino and Smith, \{Martin William\} and Morris, \{Russell E.\}",

note = "L.N.M and R.E.M wish to acknowledge the financial support from the EPSRC industrial CASE award (grant EP/N50936X/1). A.T and G.B would like to thank the financial support from the Fondo per il finanziamento delle attivit{\`a} base di ricerca (grant PJ-RIC-FFABR\_2017).",

year = "2019",

month = aug,

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doi = "10.1002/anie.201905779",

language = "English",

volume = "58",

pages = "11747--11751",

journal = "Angewandte Chemie International Edition",

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T1 - Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

AU - McHugh, Lauren N.

AU - Terracina, Angela

AU - Wheatley, Paul S.

AU - Buscarino, Gianpiero

AU - Smith, Martin William

AU - Morris, Russell E.

N1 - L.N.M and R.E.M wish to acknowledge the financial support from the EPSRC industrial CASE award (grant EP/N50936X/1). A.T and G.B would like to thank the financial support from the Fondo per il finanziamento delle attività base di ricerca (grant PJ-RIC-FFABR_2017).

PY - 2019/8/19

Y1 - 2019/8/19

N2 - Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of Toxic Industrial Chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.

AB - Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of Toxic Industrial Chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.

KW - Porous materials

KW - Metal-organic frameworks

KW - Activated carbon

KW - Gas adsorption

KW - Water stability

UR - https://www.scopus.com/pages/publications/85069720201

U2 - 10.1002/anie.201905779

DO - 10.1002/anie.201905779

M3 - Article

C2 - 31211486

SN - 1433-7851

VL - 58

SP - 11747

EP - 11751

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 34

ER -

Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

Abstract

Keywords

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Toxic gas adsorption and water stability in metal-organic frameworks

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Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

Abstract

Keywords

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Student theses

Toxic gas adsorption and water stability in metal-organic frameworks

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