Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine)

P  Lightfoot; A  Snedden

doi:10.1039/a905726i

Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)₂(bipy)] and [Co₂(mal)₂(bipy)(H₂O)₂] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine)

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Abstract

Two new metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)(2)(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-bipy-Co chains; [Co-2(mal)(2)(bipy)(H2O)(2)] is also three-dimensional, being composed of Co-mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4'-bipyridine). Both frameworks enclose small void channels.

Original language	English
Pages (from-to)	3549-3551
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/a905726i
Publication status	Published - 21 Oct 1999

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@article{b626ce95a13d4e7693b73dbed433180b,

title = "Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine)",

abstract = "Two new metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)(2)(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-bipy-Co chains; [Co-2(mal)(2)(bipy)(H2O)(2)] is also three-dimensional, being composed of Co-mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4'-bipyridine). Both frameworks enclose small void channels.",

author = "P Lightfoot and A Snedden",

year = "1999",

month = oct,

day = "21",

doi = "10.1039/a905726i",

language = "English",

pages = "3549--3551",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "20",

}

Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)₂(bipy)] and [Co₂(mal)₂(bipy)(H₂O)₂] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine). / Lightfoot, P ; Snedden, A .
In: Journal of the Chemical Society, Dalton Transactions, No. 20, 21.10.1999, p. 3549-3551.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine)

AU - Lightfoot, P

AU - Snedden, A

PY - 1999/10/21

Y1 - 1999/10/21

N2 - Two new metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)(2)(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-bipy-Co chains; [Co-2(mal)(2)(bipy)(H2O)(2)] is also three-dimensional, being composed of Co-mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4'-bipyridine). Both frameworks enclose small void channels.

AB - Two new metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)(2)(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-bipy-Co chains; [Co-2(mal)(2)(bipy)(H2O)(2)] is also three-dimensional, being composed of Co-mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4'-bipyridine). Both frameworks enclose small void channels.

UR - http://www.scopus.com/inward/record.url?scp=33748974245&partnerID=8YFLogxK

U2 - 10.1039/a905726i

DO - 10.1039/a905726i

M3 - Article

SN - 0300-9246

SP - 3549

EP - 3551

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 20

ER -

Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)₂(bipy)] and [Co₂(mal)₂(bipy)(H₂O)₂] (phth = phthalate, mal = malonate, bipy=4,4 '-bipyridine)

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