Metal adducts of diselenium dinitride

P F  Kelly; A M Z  Slawin

doi:10.1080/10426509708545653

Metal adducts of diselenium dinitride

Research output: Contribution to journal › Article › peer-review

Abstract

Adducts of diselenium dinitride, a species as yet unknown in the free state, may be prepared with either palladium or aluminium as the metal centre. Thus salts of [Pd2X6](2-) (X = Cl or Br) react with Se4N4 at 100 degrees C in CH2Cl2 to give [Pd2X6(Se2N2)](2-) while A1X(3) reacts with the same reagent, at ambient temperatures in CH2X2 to give [(A1X(3))(2)(Se2N2)]. When X = Cl in the latter case the product cannot be obtained in pure crystalline form; here we present IR data which confirms the presence of the neutral Se2N2 unit.

Original language	English
Pages (from-to)	437-440
Number of pages	4
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	124
Issue number	1
DOIs	https://doi.org/10.1080/10426509708545653
Publication status	Published - 1997

Keywords

selenium
nitride
adducts
palladium
aluminium

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10.1080/10426509708545653

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abstract = "Adducts of diselenium dinitride, a species as yet unknown in the free state, may be prepared with either palladium or aluminium as the metal centre. Thus salts of [Pd2X6](2-) (X = Cl or Br) react with Se4N4 at 100 degrees C in CH2Cl2 to give [Pd2X6(Se2N2)](2-) while A1X(3) reacts with the same reagent, at ambient temperatures in CH2X2 to give [(A1X(3))(2)(Se2N2)]. When X = Cl in the latter case the product cannot be obtained in pure crystalline form; here we present IR data which confirms the presence of the neutral Se2N2 unit.",

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author = "Kelly, {P F} and Slawin, {A M Z}",

year = "1997",

doi = "10.1080/10426509708545653",

language = "English",

volume = "124",

pages = "437--440",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

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T1 - Metal adducts of diselenium dinitride

AU - Kelly, P F

AU - Slawin, A M Z

PY - 1997

Y1 - 1997

N2 - Adducts of diselenium dinitride, a species as yet unknown in the free state, may be prepared with either palladium or aluminium as the metal centre. Thus salts of [Pd2X6](2-) (X = Cl or Br) react with Se4N4 at 100 degrees C in CH2Cl2 to give [Pd2X6(Se2N2)](2-) while A1X(3) reacts with the same reagent, at ambient temperatures in CH2X2 to give [(A1X(3))(2)(Se2N2)]. When X = Cl in the latter case the product cannot be obtained in pure crystalline form; here we present IR data which confirms the presence of the neutral Se2N2 unit.

AB - Adducts of diselenium dinitride, a species as yet unknown in the free state, may be prepared with either palladium or aluminium as the metal centre. Thus salts of [Pd2X6](2-) (X = Cl or Br) react with Se4N4 at 100 degrees C in CH2Cl2 to give [Pd2X6(Se2N2)](2-) while A1X(3) reacts with the same reagent, at ambient temperatures in CH2X2 to give [(A1X(3))(2)(Se2N2)]. When X = Cl in the latter case the product cannot be obtained in pure crystalline form; here we present IR data which confirms the presence of the neutral Se2N2 unit.

KW - selenium

KW - nitride

KW - adducts

KW - palladium

KW - aluminium

U2 - 10.1080/10426509708545653

DO - 10.1080/10426509708545653

M3 - Article

SN - 1042-6507

VL - 124

SP - 437

EP - 440

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 1

ER -

Metal adducts of diselenium dinitride

Abstract

Keywords

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