Abstract
A geometrical model describing reverse micellar systems has been developed. A single phase containing assembled structures on two different length scales is described and the hydration of surfactants involved in each structure determined. By taking into account the water-surfactant interface a transition from interconnected cylinders to spheres has been predicted and is confirmed by experimental data. Furthermore, interdigitation between reverse micelles can be predicted and observed experimentally.
| Original language | English |
|---|---|
| Pages (from-to) | 563-571 |
| Number of pages | 9 |
| Journal | New Journal of Chemistry |
| Volume | 25 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Apr 2001 |
Keywords
- SUPRA-AGGREGATION
- COMPLEX FLUIDS
- PHASE-DIAGRAM
- MICELLES
- EMULSIONS
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