Mesoporous Mn2O3 and Mn3O4 with crystalline walls

Feng Jiao, Andrew Harrison, Adrian H. Hill, Peter G. Bruce

Research output: Contribution to journalArticlepeer-review

156 Citations (Scopus)

Abstract

Ordered mesoporous; Mn2O3 and I Mn3O4 with crystalline walls (see figure) have been successfully synthesized. Mesoporous Mn2O3 was converted to Mn3O4 in a reducing atmosphere without destroying the ordered mesostructure, which gives the first example of mesoporous Mn3O4 or any reduced mesoporous manganese oxide, something that is unlikely to be achieved by direct template synthesis.

Original languageEnglish
Pages (from-to)4063-4066
Number of pages4
JournalAdvanced Materials
Volume19
Issue number22
Early online date15 Nov 2007
DOIs
Publication statusPublished - 19 Nov 2007

Keywords

  • CANTED-SPIN PROBLEM
  • MAGNETIC-PROPERTIES
  • OXIDES
  • SILICA
  • DIFFRACTION
  • TRANSITIONS
  • NANOWIRES
  • NANORODS
  • SYSTEM
  • TIO2

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