meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds

K F  Bowes; G  Ferguson; A J  Lough; C  Glidewell

doi:10.1107/S010827010300920X

meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds

K F Bowes, G Ferguson, A J Lough, C Glidewell

School of Chemistry

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Abstract

The title compound is a methanol-solvated salt, C16H38N42+.C4H4O52-.2CH(3)OH, in which the ionic components are linked into chains by two pairs of N-H...O hydrogen bonds [H...O = 1.78 - 2.21 Angstrom, N...O = 2.702 (14) - 3.094 (8) Angstrom and N - H...O = 160 - 179 degrees]. The methanol molecules are pendent from the chain and are linked to it by O - H...O hydrogen bonds [H...O = 1.86 and 1.89 Angstrom, O...O = 2.691 (9) and 2.708 (16) Angstrom, and O - H...O = 168 and 165 degrees].

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	59
DOIs	https://doi.org/10.1107/S010827010300920X
Publication status	Published - Jun 2003

Keywords

RACEMIC BUILDING-BLOCKS
SUPRAMOLECULAR CHEMISTRY
ORGANIC DIAMINES
SALTS
DIMENSIONS
ADDUCTS
ACIDS

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Bowes, K. F., Ferguson, G., Lough, A. J., & Glidewell, C. (2003). meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications, 59. https://doi.org/10.1107/S010827010300920X

@article{c521076ff3c1473d9c1d94c191642b58,

title = "meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds",

abstract = "The title compound is a methanol-solvated salt, C16H38N42+.C4H4O52-.2CH(3)OH, in which the ionic components are linked into chains by two pairs of N-H...O hydrogen bonds [H...O = 1.78 - 2.21 Angstrom, N...O = 2.702 (14) - 3.094 (8) Angstrom and N - H...O = 160 - 179 degrees]. The methanol molecules are pendent from the chain and are linked to it by O - H...O hydrogen bonds [H...O = 1.86 and 1.89 Angstrom, O...O = 2.691 (9) and 2.708 (16) Angstrom, and O - H...O = 168 and 165 degrees].",

keywords = "RACEMIC BUILDING-BLOCKS, SUPRAMOLECULAR CHEMISTRY, ORGANIC DIAMINES, SALTS, DIMENSIONS, ADDUCTS, ACIDS",

author = "Bowes, \{K F\} and G Ferguson and Lough, \{A J\} and C Glidewell",

year = "2003",

month = jun,

doi = "10.1107/S010827010300920X",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Bowes, KF, Ferguson, G, Lough, AJ & Glidewell, C 2003, 'meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds', Acta Crystallographica Section C-Crystal Structure Communications, vol. 59. https://doi.org/10.1107/S010827010300920X

meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds. / Bowes, K F ; Ferguson, G ; Lough, A J et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 59, 06.2003.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds

AU - Bowes, K F

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2003/6

Y1 - 2003/6

N2 - The title compound is a methanol-solvated salt, C16H38N42+.C4H4O52-.2CH(3)OH, in which the ionic components are linked into chains by two pairs of N-H...O hydrogen bonds [H...O = 1.78 - 2.21 Angstrom, N...O = 2.702 (14) - 3.094 (8) Angstrom and N - H...O = 160 - 179 degrees]. The methanol molecules are pendent from the chain and are linked to it by O - H...O hydrogen bonds [H...O = 1.86 and 1.89 Angstrom, O...O = 2.691 (9) and 2.708 (16) Angstrom, and O - H...O = 168 and 165 degrees].

AB - The title compound is a methanol-solvated salt, C16H38N42+.C4H4O52-.2CH(3)OH, in which the ionic components are linked into chains by two pairs of N-H...O hydrogen bonds [H...O = 1.78 - 2.21 Angstrom, N...O = 2.702 (14) - 3.094 (8) Angstrom and N - H...O = 160 - 179 degrees]. The methanol molecules are pendent from the chain and are linked to it by O - H...O hydrogen bonds [H...O = 1.86 and 1.89 Angstrom, O...O = 2.691 (9) and 2.708 (16) Angstrom, and O - H...O = 168 and 165 degrees].

KW - RACEMIC BUILDING-BLOCKS

KW - SUPRAMOLECULAR CHEMISTRY

KW - ORGANIC DIAMINES

KW - SALTS

KW - DIMENSIONS

KW - ADDUCTS

KW - ACIDS

UR - https://www.scopus.com/pages/publications/0037559301

U2 - 10.1107/S010827010300920X

DO - 10.1107/S010827010300920X

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 59

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

meso-5,5,7,12,12,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclotetradecane(S)-malate(2-)methanol disolvate: a chain of rings generated by two pairs of N-H center dot center dot center dot O hydrogen bonds

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