meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding

K F  Bowes; G  Ferguson; A J  Lough; C  Glidewell

doi:10.1107/S0108270103002804

meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding

K F Bowes, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is an ethanol-solvated salt, C16H38N42+.-2C(11)H(7)O(2)(-.)2C(2)H(6)O, in which the cation lies across a centre of inversion in P2(1)/c. The ions are linked by N-H...O hydrogen bonds [H...O = 1.70 and 2.30 Angstrom, N...O = 2.624 (2) and 3.136 (2) Angstrom, and N-H...O = 178 and 151degrees], and the ethanol molecule is linked to the anion by an O-H...O hydrogen bond [H...O = 1.90 Angstrom, O...O = 2.728 (2) Angstrom and O-H ... O = 171degrees], to form a centrosymmetric five-component aggregate. C-H...O hydrogen bonds and aromatic pi-pi-stacking interactions are absent, but the aggregates are linked into sheets by a single C-H...pi(arene) hydrogen bond.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	59
DOIs	https://doi.org/10.1107/S0108270103002804
Publication status	Published - Mar 2003

Keywords

SUPRAMOLECULAR STRUCTURES
CONFIGURATIONAL ISOMERS
2 DIMENSIONS
3 DIMENSIONS
ACID
ADDUCTS

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10.1107/S0108270103002804

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Bowes, K. F., Ferguson, G., Lough, A. J., & Glidewell, C. (2003). meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding. Acta Crystallographica Section C-Crystal Structure Communications, 59. https://doi.org/10.1107/S0108270103002804

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title = "meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding",

abstract = "The title compound is an ethanol-solvated salt, C16H38N42+.-2C(11)H(7)O(2)(-.)2C(2)H(6)O, in which the cation lies across a centre of inversion in P2(1)/c. The ions are linked by N-H...O hydrogen bonds [H...O = 1.70 and 2.30 Angstrom, N...O = 2.624 (2) and 3.136 (2) Angstrom, and N-H...O = 178 and 151degrees], and the ethanol molecule is linked to the anion by an O-H...O hydrogen bond [H...O = 1.90 Angstrom, O...O = 2.728 (2) Angstrom and O-H ... O = 171degrees], to form a centrosymmetric five-component aggregate. C-H...O hydrogen bonds and aromatic pi-pi-stacking interactions are absent, but the aggregates are linked into sheets by a single C-H...pi(arene) hydrogen bond.",

keywords = "SUPRAMOLECULAR STRUCTURES, CONFIGURATIONAL ISOMERS, 2 DIMENSIONS, 3 DIMENSIONS, ACID, ADDUCTS",

author = "Bowes, {K F} and G Ferguson and Lough, {A J} and C Glidewell",

year = "2003",

month = mar,

doi = "10.1107/S0108270103002804",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Bowes, KF, Ferguson, G, Lough, AJ & Glidewell, C 2003, 'meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding', Acta Crystallographica Section C-Crystal Structure Communications, vol. 59. https://doi.org/10.1107/S0108270103002804

meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding. / Bowes, K F ; Ferguson, G ; Lough, A J et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 59, 03.2003.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding

AU - Bowes, K F

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2003/3

Y1 - 2003/3

N2 - The title compound is an ethanol-solvated salt, C16H38N42+.-2C(11)H(7)O(2)(-.)2C(2)H(6)O, in which the cation lies across a centre of inversion in P2(1)/c. The ions are linked by N-H...O hydrogen bonds [H...O = 1.70 and 2.30 Angstrom, N...O = 2.624 (2) and 3.136 (2) Angstrom, and N-H...O = 178 and 151degrees], and the ethanol molecule is linked to the anion by an O-H...O hydrogen bond [H...O = 1.90 Angstrom, O...O = 2.728 (2) Angstrom and O-H ... O = 171degrees], to form a centrosymmetric five-component aggregate. C-H...O hydrogen bonds and aromatic pi-pi-stacking interactions are absent, but the aggregates are linked into sheets by a single C-H...pi(arene) hydrogen bond.

AB - The title compound is an ethanol-solvated salt, C16H38N42+.-2C(11)H(7)O(2)(-.)2C(2)H(6)O, in which the cation lies across a centre of inversion in P2(1)/c. The ions are linked by N-H...O hydrogen bonds [H...O = 1.70 and 2.30 Angstrom, N...O = 2.624 (2) and 3.136 (2) Angstrom, and N-H...O = 178 and 151degrees], and the ethanol molecule is linked to the anion by an O-H...O hydrogen bond [H...O = 1.90 Angstrom, O...O = 2.728 (2) Angstrom and O-H ... O = 171degrees], to form a centrosymmetric five-component aggregate. C-H...O hydrogen bonds and aromatic pi-pi-stacking interactions are absent, but the aggregates are linked into sheets by a single C-H...pi(arene) hydrogen bond.

KW - SUPRAMOLECULAR STRUCTURES

KW - CONFIGURATIONAL ISOMERS

KW - 2 DIMENSIONS

KW - 3 DIMENSIONS

KW - ACID

KW - ADDUCTS

U2 - 10.1107/S0108270103002804

DO - 10.1107/S0108270103002804

M3 - Article

SN - 1600-5759

VL - 59

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Bowes KF, Ferguson G, Lough AJ, Glidewell C. meso-5,5,7,12,12,14-Hexamethyl-1,4-diaza-8,11-diazoniacyclotetradecane bis(2-naphthoate) ethanol disolvate: centrosymmetric five-component aggregates linked into sheets by C-H center dot pi(arene) hydrogen bonding. Acta Crystallographica Section C-Crystal Structure Communications. 2003 Mar;59. doi: 10.1107/S0108270103002804