Mechanomechanically assisted hydrolysis in the ADOR process

Daniel Nikolaus Rainer; Cameron Mark Rice; Stewart James Warrender; Sharon E. Ashbrook; Russell Edward Morris

doi:10.1039/D0SC02547J

Mechanomechanically assisted hydrolysis in the ADOR process

Daniel Nikolaus Rainer, Cameron Mark Rice, Stewart James Warrender, Sharon E. Ashbrook, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

The ADOR (Assembly-Disassembly-Organisation-Reassembly) process for zeolites has been shown to produce a number of previously unknown frameworks inaccessible through conventional synthesis methods. Here, we present successful mechanochemically assisted hydrolysis of germanosilicate zeolite UTL leading to ADOR products under mild conditions, low amounts of solvent and in short reaction times. The expansion of zeolite synthesis into the realm of mechanochemistry opens up feasible pathways regarding the production of these materials, especially for industrial purposes, as well as an exciting application for economical enrichment of materials with the low natural abundance NMR-active isotope of oxygen, ¹⁷O. The results from mechanochemically assisted hydrolysis differ from those seen in the traditional ADOR approach: differences that can be attributed to a change in solvent availibility.

Original language	English
Number of pages	10
Journal	Chemical Science
Volume	Advance Article
Early online date	15 Jun 2020
DOIs	https://doi.org/10.1039/D0SC02547J
Publication status	E-pub ahead of print - 15 Jun 2020

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10.1039/D0SC02547JLicence: CC BY

Rainer_2020_CS_Mechano_CC
Copyright © 2020 The Author(s). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Final published version, 1.63 MBLicence: CC BY

H2020 ERC Advanced Grant 2017 ADOR: H2020 ERC Advanced Grant 2017 ADOR
Morris, R. E. (PI)
European Research Council
1/10/18 → 30/09/23
Project: Fellowship

Mechanochemically assisted hydrolysis in the ADOR process (dataset)
Rainer, D. N. (Creator), Rice, C. M. (Creator), Warrender, S. J. (Creator), Ashbrook, S. E. M. (Creator) & Morris, R. E. (Creator), University of St Andrews, 24 Jun 2020
DOI: 10.17630/6c2e36ec-193c-4588-91dc-620500b56d80
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abstract = "The ADOR (Assembly-Disassembly-Organisation-Reassembly) process for zeolites has been shown to produce a number of previously unknown frameworks inaccessible through conventional synthesis methods. Here, we present successful mechanochemically assisted hydrolysis of germanosilicate zeolite UTL leading to ADOR products under mild conditions, low amounts of solvent and in short reaction times. The expansion of zeolite synthesis into the realm of mechanochemistry opens up feasible pathways regarding the production of these materials, especially for industrial purposes, as well as an exciting application for economical enrichment of materials with the low natural abundance NMR-active isotope of oxygen, 17O. The results from mechanochemically assisted hydrolysis differ from those seen in the traditional ADOR approach: differences that can be attributed to a change in solvent availibility.",

author = "Rainer, {Daniel Nikolaus} and Rice, {Cameron Mark} and Warrender, {Stewart James} and Ashbrook, {Sharon E.} and Morris, {Russell Edward}",

note = "Funding: UK EPSRC (grant: EP/N509759/1) for funding of this work. D.N.R. also thanks the RSC for a Researcher Mobility Grant (no. M19-7166). R.E.M. is funded by the ERC Advanced Grant (787073 ADOR) and acknowledges the Charles University Centre of Advanced Materials (CUCAM) (OP VVV Excellent Research Teams, project number CZ.02.1.01/0.0/0.0/15_003/0000417). ",

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AU - Rainer, Daniel Nikolaus

AU - Rice, Cameron Mark

AU - Warrender, Stewart James

AU - Ashbrook, Sharon E.

AU - Morris, Russell Edward

N1 - Funding: UK EPSRC (grant: EP/N509759/1) for funding of this work. D.N.R. also thanks the RSC for a Researcher Mobility Grant (no. M19-7166). R.E.M. is funded by the ERC Advanced Grant (787073 ADOR) and acknowledges the Charles University Centre of Advanced Materials (CUCAM) (OP VVV Excellent Research Teams, project number CZ.02.1.01/0.0/0.0/15_003/0000417).

PY - 2020/6/15

Y1 - 2020/6/15

N2 - The ADOR (Assembly-Disassembly-Organisation-Reassembly) process for zeolites has been shown to produce a number of previously unknown frameworks inaccessible through conventional synthesis methods. Here, we present successful mechanochemically assisted hydrolysis of germanosilicate zeolite UTL leading to ADOR products under mild conditions, low amounts of solvent and in short reaction times. The expansion of zeolite synthesis into the realm of mechanochemistry opens up feasible pathways regarding the production of these materials, especially for industrial purposes, as well as an exciting application for economical enrichment of materials with the low natural abundance NMR-active isotope of oxygen, 17O. The results from mechanochemically assisted hydrolysis differ from those seen in the traditional ADOR approach: differences that can be attributed to a change in solvent availibility.

AB - The ADOR (Assembly-Disassembly-Organisation-Reassembly) process for zeolites has been shown to produce a number of previously unknown frameworks inaccessible through conventional synthesis methods. Here, we present successful mechanochemically assisted hydrolysis of germanosilicate zeolite UTL leading to ADOR products under mild conditions, low amounts of solvent and in short reaction times. The expansion of zeolite synthesis into the realm of mechanochemistry opens up feasible pathways regarding the production of these materials, especially for industrial purposes, as well as an exciting application for economical enrichment of materials with the low natural abundance NMR-active isotope of oxygen, 17O. The results from mechanochemically assisted hydrolysis differ from those seen in the traditional ADOR approach: differences that can be attributed to a change in solvent availibility.

U2 - 10.1039/D0SC02547J

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M3 - Article

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VL - Advance Article

JO - Chemical Science

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Mechanomechanically assisted hydrolysis in the ADOR process

Abstract

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Projects

H2020 ERC Advanced Grant 2017 ADOR: H2020 ERC Advanced Grant 2017 ADOR

Datasets

Mechanochemically assisted hydrolysis in the ADOR process (dataset)

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