Mechanisms of C-H bond activation: Rich synergy between computation and experiment

Youcef Boutadla; David L. Davies; Stuart A. MacGregor; Amalia I. Poblador-Bahamonde

doi:10.1039/b904967c

Mechanisms of C-H bond activation: Rich synergy between computation and experiment

Youcef Boutadla, David L. Davies, Stuart A. MacGregor, Amalia I. Poblador-Bahamonde

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.

Original language	English
Pages (from-to)	5820-5831
Number of pages	12
Journal	Dalton Transactions
Issue number	30
DOIs	https://doi.org/10.1039/b904967c
Publication status	Published - 10 Jun 2009

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title = "Mechanisms of C-H bond activation: Rich synergy between computation and experiment",

abstract = "Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.",

author = "Youcef Boutadla and Davies, \{David L.\} and MacGregor, \{Stuart A.\} and Poblador-Bahamonde, \{Amalia I.\}",

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AU - Boutadla, Youcef

AU - Davies, David L.

AU - MacGregor, Stuart A.

AU - Poblador-Bahamonde, Amalia I.

PY - 2009/6/10

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N2 - Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.

AB - Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.

UR - https://www.scopus.com/pages/publications/68149116128

U2 - 10.1039/b904967c

DO - 10.1039/b904967c

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AN - SCOPUS:68149116128

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SP - 5820

EP - 5831

JO - Dalton Transactions

JF - Dalton Transactions

IS - 30

ER -

Mechanisms of C-H bond activation: Rich synergy between computation and experiment

Abstract

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