TY - JOUR
T1 - Mass spectra of dihalogenocycloalkanes
AU - Ashton, D. S.
AU - Tedder, J. M.
AU - Walton, J. C.
PY - 1970/12/1
Y1 - 1970/12/1
N2 - The mass spectra of the dichloro- and bromochloro-cyclobutanes, the dichlorocyclopentanes, and the dichloro-, chlorofluoro-, and stable dibromo-cyclohexanes are reported. Four major breakdown pathways can be distinguished, the favoured fragmentation route depending on the ring size, the type of halogen substitution, the the relative position, and cis-trans-relationships of the two substituents. Within one set of isomers, the 1,1 -isomer and the cis-1,2-isomer had clearly distinguishable spectra, but the spectra of the other isomers were similar.
AB - The mass spectra of the dichloro- and bromochloro-cyclobutanes, the dichlorocyclopentanes, and the dichloro-, chlorofluoro-, and stable dibromo-cyclohexanes are reported. Four major breakdown pathways can be distinguished, the favoured fragmentation route depending on the ring size, the type of halogen substitution, the the relative position, and cis-trans-relationships of the two substituents. Within one set of isomers, the 1,1 -isomer and the cis-1,2-isomer had clearly distinguishable spectra, but the spectra of the other isomers were similar.
UR - http://www.scopus.com/inward/record.url?scp=37049120457&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:37049120457
SN - 0045-6470
SP - 1775
EP - 1780
JO - Journal of the Chemical Society B: Physical Organic
JF - Journal of the Chemical Society B: Physical Organic
ER -