Manufacturing and electrochemical evaluation of sofcroll with the La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ anode

K. Nowicki; H. Zeng; J. T.S. Irvine

doi:10.1149/09101.0139ecst

Manufacturing and electrochemical evaluation of sofcroll with the La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ - Zr_0.92Y_0.08O_2-γ anode

K. Nowicki, H. Zeng, J. T.S. Irvine

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

SOFCRoll is a self-supporting, double spiral design combining the advantages of the planar system, thick film manufacturing techniques and robustness of the tubular design. SOFCRoll cells are produced entirely by tape casting and co-sintering, with a volume of less than 2.5cm³ and a large active surface area that exceeding 20cm². We are currently investigating the incorporation of the A-site deficient, nickel doped perovskite La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ into the SOFCRoll. In the SOFCRoll with La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ - Zr_0.92Y_0.08O_2-γ fuel electrode, the Zr_0.92Y_0.08O_2-γ electrolyte and (La_0.8Sr_0.2)_0.95MnO₃ - Zr_0.92Y_0.08O_2-γ oxygen electrode, the electrochemical poling at 2.3V for a few minutes triggered exsolution of nickel nanoparticles and increased the power density. This paper will present the complete methodology behind SOFCRoll manufacture and ceramic processing, with the results of microstructure analysis, shrinking of individual components and recent performance tests.

Original language	English
Title of host publication	Solid Oxide Fuel Cells 16, SOFC XVI
Editors	K. Eguchi, S. C. Singhal
Publisher	Electrochemical Society, Inc.
Pages	139-148
Number of pages	10
Edition	1
ISBN (Electronic)	9781607685395
DOIs	https://doi.org/10.1149/09101.0139ecst
Publication status	Published - 8 Sept 2019
Event	16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI - Kyoto, Japan Duration: 8 Sept 2019 → 13 Sept 2019 Conference number: 16 http://www.eguchi-lab.ehcc.kyoto-u.ac.jp/SOFC_XVI/

Publication series

Name	ECS Transactions
Number	1
Volume	91
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI
Abbreviated title	SOFC
Country/Territory	Japan
City	Kyoto
Period	8/09/19 → 13/09/19
Internet address	http://www.eguchi-lab.ehcc.kyoto-u.ac.jp/SOFC_XVI/

Access to Document

10.1149/09101.0139ecst

Cite this

Nowicki, K., Zeng, H., & Irvine, J. T. S. (2019). Manufacturing and electrochemical evaluation of sofcroll with the La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ - Zr_0.92Y_0.08O_2-γ anode. In K. Eguchi, & S. C. Singhal (Eds.), Solid Oxide Fuel Cells 16, SOFC XVI (1 ed., pp. 139-148). (ECS Transactions; Vol. 91, No. 1). Electrochemical Society, Inc.. https://doi.org/10.1149/09101.0139ecst

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title = "Manufacturing and electrochemical evaluation of sofcroll with the La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ anode",

abstract = "SOFCRoll is a self-supporting, double spiral design combining the advantages of the planar system, thick film manufacturing techniques and robustness of the tubular design. SOFCRoll cells are produced entirely by tape casting and co-sintering, with a volume of less than 2.5cm3 and a large active surface area that exceeding 20cm2. We are currently investigating the incorporation of the A-site deficient, nickel doped perovskite La0.43Ca0.37Ni0.06Ti0.94O3-γ into the SOFCRoll. In the SOFCRoll with La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ fuel electrode, the Zr0.92Y0.08O2-γ electrolyte and (La0.8Sr0.2)0.95MnO3 - Zr0.92Y0.08O2-γ oxygen electrode, the electrochemical poling at 2.3V for a few minutes triggered exsolution of nickel nanoparticles and increased the power density. This paper will present the complete methodology behind SOFCRoll manufacture and ceramic processing, with the results of microstructure analysis, shrinking of individual components and recent performance tests.",

author = "K. Nowicki and H. Zeng and Irvine, {J. T.S.}",

year = "2019",

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doi = "10.1149/09101.0139ecst",

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note = "16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI, SOFC ; Conference date: 08-09-2019 Through 13-09-2019",

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Nowicki, K, Zeng, H & Irvine, JTS 2019, Manufacturing and electrochemical evaluation of sofcroll with the La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ - Zr_0.92Y_0.08O_2-γ anode. in K Eguchi & SC Singhal (eds), Solid Oxide Fuel Cells 16, SOFC XVI. 1 edn, ECS Transactions, no. 1, vol. 91, Electrochemical Society, Inc., pp. 139-148, 16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI, Kyoto, Japan, 8/09/19. https://doi.org/10.1149/09101.0139ecst

Manufacturing and electrochemical evaluation of sofcroll with the La_0.43Ca_0.37Ni_0.06Ti_0.94O_3-γ - Zr_0.92Y_0.08O_2-γ anode. / Nowicki, K.; Zeng, H.; Irvine, J. T.S.
Solid Oxide Fuel Cells 16, SOFC XVI. ed. / K. Eguchi; S. C. Singhal. 1. ed. Electrochemical Society, Inc., 2019. p. 139-148 (ECS Transactions; Vol. 91, No. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Manufacturing and electrochemical evaluation of sofcroll with the La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ anode

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AU - Zeng, H.

AU - Irvine, J. T.S.

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N2 - SOFCRoll is a self-supporting, double spiral design combining the advantages of the planar system, thick film manufacturing techniques and robustness of the tubular design. SOFCRoll cells are produced entirely by tape casting and co-sintering, with a volume of less than 2.5cm3 and a large active surface area that exceeding 20cm2. We are currently investigating the incorporation of the A-site deficient, nickel doped perovskite La0.43Ca0.37Ni0.06Ti0.94O3-γ into the SOFCRoll. In the SOFCRoll with La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ fuel electrode, the Zr0.92Y0.08O2-γ electrolyte and (La0.8Sr0.2)0.95MnO3 - Zr0.92Y0.08O2-γ oxygen electrode, the electrochemical poling at 2.3V for a few minutes triggered exsolution of nickel nanoparticles and increased the power density. This paper will present the complete methodology behind SOFCRoll manufacture and ceramic processing, with the results of microstructure analysis, shrinking of individual components and recent performance tests.

AB - SOFCRoll is a self-supporting, double spiral design combining the advantages of the planar system, thick film manufacturing techniques and robustness of the tubular design. SOFCRoll cells are produced entirely by tape casting and co-sintering, with a volume of less than 2.5cm3 and a large active surface area that exceeding 20cm2. We are currently investigating the incorporation of the A-site deficient, nickel doped perovskite La0.43Ca0.37Ni0.06Ti0.94O3-γ into the SOFCRoll. In the SOFCRoll with La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ fuel electrode, the Zr0.92Y0.08O2-γ electrolyte and (La0.8Sr0.2)0.95MnO3 - Zr0.92Y0.08O2-γ oxygen electrode, the electrochemical poling at 2.3V for a few minutes triggered exsolution of nickel nanoparticles and increased the power density. This paper will present the complete methodology behind SOFCRoll manufacture and ceramic processing, with the results of microstructure analysis, shrinking of individual components and recent performance tests.

U2 - 10.1149/09101.0139ecst

DO - 10.1149/09101.0139ecst

M3 - Conference contribution

AN - SCOPUS:85073189240

T3 - ECS Transactions

SP - 139

EP - 148

BT - Solid Oxide Fuel Cells 16, SOFC XVI

A2 - Eguchi, K.

A2 - Singhal, S. C.

PB - Electrochemical Society, Inc.

T2 - 16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI

Y2 - 8 September 2019 through 13 September 2019

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