Manipulating Replication Processes within a Dynamic Covalent Framework

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34 Citations (Scopus)

Abstract

The reaction of an amine bearing an amidopyridine recognition site and an aldehyde bearing a carboxylic acid recognition site affords an imine that is capable of directing its own formation through a dynamic covalent replication cycle. Additionally, the amine, formed by reduction of the replicating imine, is a more efficient catalyst for the formation of the replicating imine than the imine is a catalyst for its own formation.

Original languageEnglish
Pages (from-to)4589-4592
Number of pages4
JournalOrganic Letters
Volume10
Issue number20
DOIs
Publication statusPublished - 16 Oct 2008

Keywords

  • VIRTUAL COMBINATORIAL LIBRARIES
  • SYSTEMS CHEMISTRY
  • SELF-REPLICATION
  • THERMODYNAMIC CONTROL
  • EFFECTIVE MOLARITIES
  • AQUEOUS-SOLUTION
  • SUBSTITUTION
  • SELECTIVITY
  • GENERATION
  • CATALYSIS

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