Manganese complexes of phosphino-μ-phosphido ligands

Peter G. Edwards, F. Ekkehardt Hahn, Matthieu Limon, Paul D. Newman, Benson M. Kariuki, Andreas Stasch

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The reaction of the manganese precursors [MnOTf(CO)3{1,2- (PH2)2C6H4}], 5, or [MnOTf(CO) 3{1,2-(PH2)2C2H4}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.

Original languageEnglish
Pages (from-to)5115-5119
Number of pages5
JournalDalton Transactions
Issue number26
DOIs
Publication statusPublished - 2009

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