Manganese complexes of phosphino-μ-phosphido ligands

Peter G. Edwards; F. Ekkehardt Hahn; Matthieu Limon; Paul D. Newman; Benson M. Kariuki; Andreas Stasch

doi:10.1039/b822870a

Manganese complexes of phosphino-μ-phosphido ligands

Peter G. Edwards, F. Ekkehardt Hahn, Matthieu Limon, Paul D. Newman, Benson M. Kariuki, Andreas Stasch

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the manganese precursors [MnOTf(CO)₃{1,2- (PH₂)₂C₆H₄}], 5, or [MnOTf(CO) ₃{1,2-(PH₂)₂C₂H₄}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.

Original language	English
Pages (from-to)	5115-5119
Number of pages	5
Journal	Dalton Transactions
Issue number	26
DOIs	https://doi.org/10.1039/b822870a
Publication status	Published - 2009

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title = "Manganese complexes of phosphino-μ-phosphido ligands",

abstract = "The reaction of the manganese precursors [MnOTf(CO)3{1,2- (PH2)2C6H4}], 5, or [MnOTf(CO) 3{1,2-(PH2)2C2H4}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.",

author = "Edwards, {Peter G.} and Hahn, {F. Ekkehardt} and Matthieu Limon and Newman, {Paul D.} and Kariuki, {Benson M.} and Andreas Stasch",

year = "2009",

doi = "10.1039/b822870a",

language = "English",

pages = "5115--5119",

journal = "Dalton Transactions",

issn = "1477-9226",

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T1 - Manganese complexes of phosphino-μ-phosphido ligands

AU - Edwards, Peter G.

AU - Hahn, F. Ekkehardt

AU - Limon, Matthieu

AU - Newman, Paul D.

AU - Kariuki, Benson M.

AU - Stasch, Andreas

PY - 2009

Y1 - 2009

N2 - The reaction of the manganese precursors [MnOTf(CO)3{1,2- (PH2)2C6H4}], 5, or [MnOTf(CO) 3{1,2-(PH2)2C2H4}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.

AB - The reaction of the manganese precursors [MnOTf(CO)3{1,2- (PH2)2C6H4}], 5, or [MnOTf(CO) 3{1,2-(PH2)2C2H4}], 6, with either the silver complex of 1,3-diallylbenzimidazol-2-ylidiene or the free carbene, resulted in the formation of the new, dimeric phosphino-μ-phosphido manganese species 7 and 8. Complex 7 crystallises in two isomeric forms (cis and trans), depending upon the choice of solvent. The structures of both isomers have been determined by single-crystal X-ray techniques.

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DO - 10.1039/b822870a

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AN - SCOPUS:67649716556

SN - 1477-9226

SP - 5115

EP - 5119

JO - Dalton Transactions

JF - Dalton Transactions

IS - 26

ER -

Manganese complexes of phosphino-μ-phosphido ligands

Abstract

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