Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Uttam Kumar Das; Trevor Janes; Amit Kumar; David Milstein

doi:10.1039/D0GC00570C

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Uttam Kumar Das
, Trevor Janes
, Amit Kumar
, David Milstein

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

Original language	English
Pages (from-to)	3079-3082
Journal	Green Chemistry
Volume	22
Issue number	10
Early online date	19 Mar 2020
DOIs	https://doi.org/10.1039/D0GC00570C
Publication status	Published - 21 May 2020

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Das_2020_GC_Manganese_AAM
Copyright © 2020 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D0GC00570C
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title = "Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines",

abstract = "Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.",

author = "Das, \{Uttam Kumar\} and Trevor Janes and Amit Kumar and David Milstein",

note = "U. K. D. is thankful to Govt. of India for the DST SERB Overseas Postdoctoral Fellowship. T. J. thanks the Azrieli Foundation for a postdoctoral fellowship and A.K. thanks the Planning and Budgeting Committee (PBC) for a postdoctoral fellowship. D.M. is the Israel Matz Professorial Chair of Organic Chemistry.",

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doi = "10.1039/D0GC00570C",

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AU - Das, Uttam Kumar

AU - Janes, Trevor

AU - Kumar, Amit

AU - Milstein, David

N1 - U. K. D. is thankful to Govt. of India for the DST SERB Overseas Postdoctoral Fellowship. T. J. thanks the Azrieli Foundation for a postdoctoral fellowship and A.K. thanks the Planning and Budgeting Committee (PBC) for a postdoctoral fellowship. D.M. is the Israel Matz Professorial Chair of Organic Chemistry.

PY - 2020/5/21

Y1 - 2020/5/21

N2 - Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

AB - Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

U2 - 10.1039/D0GC00570C

DO - 10.1039/D0GC00570C

M3 - Article

SN - 1463-9262

VL - 22

SP - 3079

EP - 3082

JO - Green Chemistry

JF - Green Chemistry

IS - 10

ER -

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

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