Manganese-catalysed transfer hydrogenation of esters

Conor Oates; Magnus B. Widegren; Matt  Clarke

doi:10.1039/D0CC02598D

Manganese-catalysed transfer hydrogenation of esters

Conor Oates, Magnus B. Widegren, Matt Clarke

Research output: Contribution to journal › Article › peer-review

Abstract

Manganese catalysed ester reduction using ethanol as reductant in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promotor. The catalyst is derived from a tridentate P,N,N ligand.

Original language	English
Pages (from-to)	8635-8638
Journal	Chemical Communications
Volume	56
Issue number	61
Early online date	11 Jun 2020
DOIs	https://doi.org/10.1039/D0CC02598D
Publication status	Published - 7 Aug 2020

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10.1039/D0CC02598DLicence: CC BY

Oates_2020_CC_Manganese_CC
Copyright © 2020 The Author(s). Open Access article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Final published version, 1.6 MBLicence: CC BY

CRITICAT - Delivery of Teach & Training: CRITICAT - Delivery of Teaching & Technical Training
Smith, A. D. (PI)
EPSRC
1/05/14 → 31/10/22
Project: Standard

Manganese-Catalysed Transfer Hydrogenation of Esters (dataset)
Oates, C. (Creator), Widegren, M. B. (Contributor) & Clarke, M. (Supervisor), University of St Andrews, 2020
DOI: 10.17630/0a645625-3a7a-47ed-9f6d-63ef3b998d79
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title = "Manganese-catalysed transfer hydrogenation of esters",

abstract = "Manganese catalysed ester reduction using ethanol as reductant in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promotor. The catalyst is derived from a tridentate P,N,N ligand.",

author = "Conor Oates and Widegren, {Magnus B.} and Matt Clarke",

note = "Authors thank the University of St Andrews, and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT) for financial support [Ph.D. studentship to CO; Grant code: EP/L016419/1].",

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language = "English",

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AU - Oates, Conor

AU - Widegren, Magnus B.

AU - Clarke, Matt

N1 - Authors thank the University of St Andrews, and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT) for financial support [Ph.D. studentship to CO; Grant code: EP/L016419/1].

PY - 2020/8/7

Y1 - 2020/8/7

N2 - Manganese catalysed ester reduction using ethanol as reductant in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promotor. The catalyst is derived from a tridentate P,N,N ligand.

AB - Manganese catalysed ester reduction using ethanol as reductant in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promotor. The catalyst is derived from a tridentate P,N,N ligand.

U2 - 10.1039/D0CC02598D

DO - 10.1039/D0CC02598D

M3 - Article

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SP - 8635

EP - 8638

JO - Chemical Communications

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Manganese-catalysed transfer hydrogenation of esters

Abstract

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Projects

CRITICAT - Delivery of Teach & Training: CRITICAT - Delivery of Teaching & Technical Training

Datasets

Manganese-Catalysed Transfer Hydrogenation of Esters (dataset)

Cite this