Manganese catalysed enantioselective hydrogenation of in-situ-synthesised imines: efficient asymmetric synthesis of amino-indane derivatives

Conor Oates, Alister S. Goodfellow, Michael Buehl, Matt Clarke*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)
5 Downloads (Pure)

Abstract

A manganese catalyst of a facially coordinating P,N,N ligand catalyses the hydrogenation of imines derived from indanone derivatives with high enantioselectivity. There is no requirement for an activating group and imines can be generated in situ. The selectivity can be rationalised by DFT calculations.
Original languageEnglish
Pages (from-to)3864-3868
Number of pages5
JournalGreen Chemistry
Volume25
Issue number10
Early online date3 May 2023
DOIs
Publication statusPublished - 21 May 2023

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