MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]

SMSV DOIDGEHARRISON; RA HOWIE; John Thomas Sirr Irvine; JL WARDELL

MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]

SMSV DOIDGEHARRISON, RA HOWIE, John Thomas Sirr Irvine, JL WARDELL

Research output: Contribution to journal › Article › peer-review

Abstract

Compounds [Bu4N]2[X2Sn(DMIT)2] [X = Br (4) or 1 (5); H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione] have been prepared from [Bu4N]2[Zn(DMIT)2] and SnX4 in the presence of Bu4NBr. A crystal structure determination of 5 revealed it to consist of discrete [Bu4N] cations and [I2Sn(DMIT)2] dianions; the geometry about tin in the dianion is octahedral with chelating DMIT ligands and cis-iodide ligands [Sn-I = 2.724(5) and 2.727(3) angstrom; mean Sn-S (trans to I) = 2.560 angstrom and mean Sn-S (trans to S) = 2.530 angstrom]. The chelate bite angles are 82.9(4) and 83.1(4)-degrees.

Original language	English
Pages (from-to)	2223-2229
Number of pages	7
Journal	Polyhedron
Volume	11
Issue number	17
Publication status	Published - Sept 1992

Keywords

SUPERCONDUCTOR
TRANSITION
MOLECULAR-STRUCTURE
LIGANDS
CHEMISTRY
X-RAY
COMPLEXES

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@article{4477cae487b04499a25810412da9e788,

title = "MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]",

abstract = "Compounds [Bu4N]2[X2Sn(DMIT)2] [X = Br (4) or 1 (5); H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione] have been prepared from [Bu4N]2[Zn(DMIT)2] and SnX4 in the presence of Bu4NBr. A crystal structure determination of 5 revealed it to consist of discrete [Bu4N] cations and [I2Sn(DMIT)2] dianions; the geometry about tin in the dianion is octahedral with chelating DMIT ligands and cis-iodide ligands [Sn-I = 2.724(5) and 2.727(3) angstrom; mean Sn-S (trans to I) = 2.560 angstrom and mean Sn-S (trans to S) = 2.530 angstrom]. The chelate bite angles are 82.9(4) and 83.1(4)-degrees.",

keywords = "SUPERCONDUCTOR, TRANSITION, MOLECULAR-STRUCTURE, LIGANDS, CHEMISTRY, X-RAY, COMPLEXES",

author = "SMSV DOIDGEHARRISON and RA HOWIE and Irvine, {John Thomas Sirr} and JL WARDELL",

year = "1992",

month = sep,

language = "English",

volume = "11",

pages = "2223--2229",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "17",

}

MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]. / DOIDGEHARRISON, SMSV; HOWIE, RA; Irvine, John Thomas Sirr et al.
In: Polyhedron, Vol. 11, No. 17, 09.1992, p. 2223-2229.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]

AU - DOIDGEHARRISON, SMSV

AU - HOWIE, RA

AU - Irvine, John Thomas Sirr

AU - WARDELL, JL

PY - 1992/9

Y1 - 1992/9

N2 - Compounds [Bu4N]2[X2Sn(DMIT)2] [X = Br (4) or 1 (5); H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione] have been prepared from [Bu4N]2[Zn(DMIT)2] and SnX4 in the presence of Bu4NBr. A crystal structure determination of 5 revealed it to consist of discrete [Bu4N] cations and [I2Sn(DMIT)2] dianions; the geometry about tin in the dianion is octahedral with chelating DMIT ligands and cis-iodide ligands [Sn-I = 2.724(5) and 2.727(3) angstrom; mean Sn-S (trans to I) = 2.560 angstrom and mean Sn-S (trans to S) = 2.530 angstrom]. The chelate bite angles are 82.9(4) and 83.1(4)-degrees.

AB - Compounds [Bu4N]2[X2Sn(DMIT)2] [X = Br (4) or 1 (5); H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione] have been prepared from [Bu4N]2[Zn(DMIT)2] and SnX4 in the presence of Bu4NBr. A crystal structure determination of 5 revealed it to consist of discrete [Bu4N] cations and [I2Sn(DMIT)2] dianions; the geometry about tin in the dianion is octahedral with chelating DMIT ligands and cis-iodide ligands [Sn-I = 2.724(5) and 2.727(3) angstrom; mean Sn-S (trans to I) = 2.560 angstrom and mean Sn-S (trans to S) = 2.530 angstrom]. The chelate bite angles are 82.9(4) and 83.1(4)-degrees.

KW - SUPERCONDUCTOR

KW - TRANSITION

KW - MOLECULAR-STRUCTURE

KW - LIGANDS

KW - CHEMISTRY

KW - X-RAY

KW - COMPLEXES

M3 - Article

SN - 0277-5387

VL - 11

SP - 2223

EP - 2229

JO - Polyhedron

JF - Polyhedron

IS - 17

ER -