Main group complexes of aminophenol. The x-ray structure of Sn[C6H4(NH2)(O)]2cl2

D A  Lewis; D J  Williams; A M  Slawin; J D  Woollins

doi:10.1016/0277-5387(95)00279-2

Main group complexes of aminophenol. The x-ray structure of Sn[C6H4(NH2)(O)]2cl2

D A Lewis, D J Williams, A M Slawin, J D Woollins

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Deprotonation of aminophenol (ampH(3)) followed by reaction with SnCl4 . 5H(2)O or Al(OPri)(3) gives Sn(ampH(2))(2)Cl-2 (1) and Al(ampH(2))(3) (2). The X-ray structure of 1 reveals cis, cis, trans coordination, although in solution the Sn-119 NMR indicates a mixture of isomers.

Original language	English
Pages (from-to)	555-558
Number of pages	4
Journal	Polyhedron
Volume	15
Issue number	3
DOIs	https://doi.org/10.1016/0277-5387(95)00279-2
Publication status	Published - Feb 1996

Keywords

PEROXO COMPLEXES
ORGANIC-LIGANDS

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title = "Main group complexes of aminophenol. The x-ray structure of Sn[C6H4(NH2)(O)]2cl2",

abstract = "Deprotonation of aminophenol (ampH(3)) followed by reaction with SnCl4 . 5H(2)O or Al(OPri)(3) gives Sn(ampH(2))(2)Cl-2 (1) and Al(ampH(2))(3) (2). The X-ray structure of 1 reveals cis, cis, trans coordination, although in solution the Sn-119 NMR indicates a mixture of isomers.",

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author = "Lewis, {D A} and Williams, {D J} and Slawin, {A M} and Woollins, {J D}",

year = "1996",

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T1 - Main group complexes of aminophenol. The x-ray structure of Sn[C6H4(NH2)(O)]2cl2

AU - Lewis, D A

AU - Williams, D J

AU - Slawin, A M

AU - Woollins, J D

PY - 1996/2

Y1 - 1996/2

N2 - Deprotonation of aminophenol (ampH(3)) followed by reaction with SnCl4 . 5H(2)O or Al(OPri)(3) gives Sn(ampH(2))(2)Cl-2 (1) and Al(ampH(2))(3) (2). The X-ray structure of 1 reveals cis, cis, trans coordination, although in solution the Sn-119 NMR indicates a mixture of isomers.

AB - Deprotonation of aminophenol (ampH(3)) followed by reaction with SnCl4 . 5H(2)O or Al(OPri)(3) gives Sn(ampH(2))(2)Cl-2 (1) and Al(ampH(2))(3) (2). The X-ray structure of 1 reveals cis, cis, trans coordination, although in solution the Sn-119 NMR indicates a mixture of isomers.

KW - PEROXO COMPLEXES

KW - ORGANIC-LIGANDS

U2 - 10.1016/0277-5387(95)00279-2

DO - 10.1016/0277-5387(95)00279-2

M3 - Comment/debate

SN - 0277-5387

VL - 15

SP - 555

EP - 558

JO - Polyhedron

JF - Polyhedron

IS - 3

ER -

Main group complexes of aminophenol. The x-ray structure of Sn[C6H4(NH2)(O)]2cl2

Abstract

Keywords

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