Luminescent Hyperbranched Polymers:  Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation

Dominik Konkolewicz; Sylvain Gailllard; Andrew G. West; Yuen Yap Cheng; Angus Gray-Weale; Timothy W. Schmidt; Steven Patrick Nolan; Sebastien Perrier

doi:10.1021/om200103f

Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation

Dominik Konkolewicz, Sylvain Gailllard, Andrew G. West, Yuen Yap Cheng, Angus Gray-Weale, Timothy W. Schmidt, Steven Patrick Nolan, Sebastien Perrier

Research output: Contribution to journal › Article › peer-review

Abstract

ABSTRACT: A highly efficient and straightforward synthetic
method, leading to the formation of a luminescent hyperbranched
polymer, is described. The simple polymer functionalization
step takes advantage of the reactivity of relatively
acidic alkyne C-H bonds with a basic [Au(NHC)(OH)]
(NHC = N-heterocyclic carbene) synthon.

Original language	English
Pages (from-to)	1315 - 1318
Number of pages	4
Journal	Organometallics
Volume	30
DOIs	https://doi.org/10.1021/om200103f
Publication status	Published - 11 Feb 2011

Access to Document

10.1021/om200103f

Cite this

@article{ef0d4002b9714e05ae0ca30f737e2eff,

title = "Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation",

abstract = "ABSTRACT: A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyperbranched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon.",

author = "Dominik Konkolewicz and Sylvain Gailllard and West, \{Andrew G.\} and Cheng, \{Yuen Yap\} and Angus Gray-Weale and Schmidt, \{Timothy W.\} and Nolan, \{Steven Patrick\} and Sebastien Perrier",

year = "2011",

month = feb,

day = "11",

doi = "10.1021/om200103f",

language = "English",

volume = "30",

pages = "1315 -- 1318",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

}

TY - JOUR

T1 - Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation

AU - Konkolewicz, Dominik

AU - Gailllard, Sylvain

AU - West, Andrew G.

AU - Cheng, Yuen Yap

AU - Gray-Weale, Angus

AU - Schmidt, Timothy W.

AU - Nolan, Steven Patrick

AU - Perrier, Sebastien

PY - 2011/2/11

Y1 - 2011/2/11

N2 - ABSTRACT: A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyperbranched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon.

AB - ABSTRACT: A highly efficient and straightforward synthetic method, leading to the formation of a luminescent hyperbranched polymer, is described. The simple polymer functionalization step takes advantage of the reactivity of relatively acidic alkyne C-H bonds with a basic [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) synthon.

UR - https://www.scopus.com/pages/publications/79952947071

U2 - 10.1021/om200103f

DO - 10.1021/om200103f

M3 - Article

SN - 0276-7333

VL - 30

SP - 1315

EP - 1318

JO - Organometallics

JF - Organometallics

ER -

Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation

Abstract

Access to Document

Other files and links

Fingerprint

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

Cite this

Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation

Abstract

Access to Document

Other files and links

Fingerprint

Projects

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

Cite this