Luminescence from inter-chain aggregates in polythiophene films

A Ruseckas; E Namdas; M Theander; M Svensson; A Yartsev; D Zigmantas; MR Andersson; O Inganas; null Sundstrom

Luminescence from inter-chain aggregates in polythiophene films

A Ruseckas, E Namdas, M Theander, M Svensson, A Yartsev, D Zigmantas, MR Andersson, O Inganas, Sundstrom

School of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

We report time-resolved photoluminescence of two polythiophene derivatives with different chain packing. Emission of inter-chain aggregates is distinguished from that of intra-chain singlet excitons. The aggregate luminescence is shifted towards lower energies relative to that of intra-chain exciton by 0.17 eV, and the Huang-Rhys factor of the coupling to the intra-chain C double bondC vibration is S = 1.5. The excitonic coupling in aggregates is of intermediate strength.

Original language	English
Pages (from-to)	603-604
Number of pages	2
Journal	Synthetic Metals
Volume	119
Issue number	1-3
Publication status	Published - 15 Mar 2001
Event	16th International Conference on Science and Technology of Synthetic Metals (ICSM 2000) - GASTEIN, Austria Duration: 15 Jul 2000 → 21 Jul 2000

Keywords

photoluminescence
time-resolved fast spectroscopy
polythiophene and derivatives
CONJUGATED POLYMERS
PAIRS

Cite this

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title = "Luminescence from inter-chain aggregates in polythiophene films",

abstract = "We report time-resolved photoluminescence of two polythiophene derivatives with different chain packing. Emission of inter-chain aggregates is distinguished from that of intra-chain singlet excitons. The aggregate luminescence is shifted towards lower energies relative to that of intra-chain exciton by 0.17 eV, and the Huang-Rhys factor of the coupling to the intra-chain C double bondC vibration is S = 1.5. The excitonic coupling in aggregates is of intermediate strength.",

keywords = "photoluminescence, time-resolved fast spectroscopy, polythiophene and derivatives, CONJUGATED POLYMERS, PAIRS",

author = "A Ruseckas and E Namdas and M Theander and M Svensson and A Yartsev and D Zigmantas and MR Andersson and O Inganas and Sundstrom",

year = "2001",

month = mar,

day = "15",

language = "English",

volume = "119",

pages = "603--604",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "ELSEVIER SCIENCE SA",

number = "1-3",

note = "16th International Conference on Science and Technology of Synthetic Metals (ICSM 2000) ; Conference date: 15-07-2000 Through 21-07-2000",

}

TY - JOUR

T1 - Luminescence from inter-chain aggregates in polythiophene films

AU - Ruseckas, A

AU - Namdas, E

AU - Theander, M

AU - Svensson, M

AU - Yartsev, A

AU - Zigmantas, D

AU - Andersson, MR

AU - Inganas, O

AU - Sundstrom, null

PY - 2001/3/15

Y1 - 2001/3/15

N2 - We report time-resolved photoluminescence of two polythiophene derivatives with different chain packing. Emission of inter-chain aggregates is distinguished from that of intra-chain singlet excitons. The aggregate luminescence is shifted towards lower energies relative to that of intra-chain exciton by 0.17 eV, and the Huang-Rhys factor of the coupling to the intra-chain C double bondC vibration is S = 1.5. The excitonic coupling in aggregates is of intermediate strength.

AB - We report time-resolved photoluminescence of two polythiophene derivatives with different chain packing. Emission of inter-chain aggregates is distinguished from that of intra-chain singlet excitons. The aggregate luminescence is shifted towards lower energies relative to that of intra-chain exciton by 0.17 eV, and the Huang-Rhys factor of the coupling to the intra-chain C double bondC vibration is S = 1.5. The excitonic coupling in aggregates is of intermediate strength.

KW - photoluminescence

KW - time-resolved fast spectroscopy

KW - polythiophene and derivatives

KW - CONJUGATED POLYMERS

KW - PAIRS

M3 - Article

SN - 0379-6779

VL - 119

SP - 603

EP - 604

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

T2 - 16th International Conference on Science and Technology of Synthetic Metals (ICSM 2000)

Y2 - 15 July 2000 through 21 July 2000

ER -

Luminescence from inter-chain aggregates in polythiophene films

Abstract

Keywords

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