Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro-alkyl motifs

Marcello Nicoletti; Matthias Bremer; Peer Kirsch; David O'Hagan

doi:10.1039/b711839b

Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro-alkyl motifs

Marcello Nicoletti, Matthias Bremer, Peer Kirsch^*, David O'Hagan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of the stereospecifically fluorinated difluoro- and trifluoro-rac-3 and rac-4 is described where the fluorine atoms are positioned adjacent/vicinal to each other and the physical characteristics of these candidate liquid crystals including negative dielectric anisotropy are measured and rationalised.

Original language	English
Pages (from-to)	5075-5077
Number of pages	3
Journal	Chemical Communications
Issue number	47
DOIs	https://doi.org/10.1039/b711839b
Publication status	Published - 2007

Keywords

NEGATIVE DIELECTRIC ANISOTROPY
CONFORMATION
DESIGN
ACIDS

Access to Document

10.1039/b711839b

EP/C536347/1: The C-F bond as a conformational tool in biological and materials chemistry
O'Hagan, D. (PI)
EPSRC
22/08/05 → 21/08/08
Project: Standard

Cite this

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title = "Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro-alkyl motifs",

abstract = "The synthesis of the stereospecifically fluorinated difluoro- and trifluoro-rac-3 and rac-4 is described where the fluorine atoms are positioned adjacent/vicinal to each other and the physical characteristics of these candidate liquid crystals including negative dielectric anisotropy are measured and rationalised.",

keywords = "NEGATIVE DIELECTRIC ANISOTROPY, CONFORMATION, DESIGN, ACIDS",

author = "Marcello Nicoletti and Matthias Bremer and Peer Kirsch and David O'Hagan",

year = "2007",

doi = "10.1039/b711839b",

language = "English",

pages = "5075--5077",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "47",

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T1 - Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro-alkyl motifs

AU - Nicoletti, Marcello

AU - Bremer, Matthias

AU - Kirsch, Peer

AU - O'Hagan, David

PY - 2007

Y1 - 2007

N2 - The synthesis of the stereospecifically fluorinated difluoro- and trifluoro-rac-3 and rac-4 is described where the fluorine atoms are positioned adjacent/vicinal to each other and the physical characteristics of these candidate liquid crystals including negative dielectric anisotropy are measured and rationalised.

AB - The synthesis of the stereospecifically fluorinated difluoro- and trifluoro-rac-3 and rac-4 is described where the fluorine atoms are positioned adjacent/vicinal to each other and the physical characteristics of these candidate liquid crystals including negative dielectric anisotropy are measured and rationalised.

KW - NEGATIVE DIELECTRIC ANISOTROPY

KW - CONFORMATION

KW - DESIGN

KW - ACIDS

U2 - 10.1039/b711839b

DO - 10.1039/b711839b

M3 - Article

SN - 1359-7345

SP - 5075

EP - 5077

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Liquid crystals carrying stereodefined vicinal difluoro- and trifluoro-alkyl motifs

Abstract

Keywords

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Projects

EP/C536347/1: The C-F bond as a conformational tool in biological and materials chemistry

Cite this