(La0.75Sr0.25)0.95Mn0.5Cr0.5O3 as the Cathode of Solid Oxide Electrolysis Cells for High Temperature Hydrogen Production from Steam

John Thomas Sirr Irvine, Michael Anthony Wolfe

Research output: Contribution to journalArticlepeer-review

178 Citations (Scopus)

Abstract

Ni/YSZ cathodes are generally utilised for steam electrolysis; however such electrodes can only operate under reducing conditions. In an atmosphere with low content of H-2 or without H2, especially under low current conditions, cathodes based on (La0.75Sr0.25)(0.95)Mn0.5Cr0.5O3 (LSCM) provide a promising alternative. Solid Oxide Electrolysis Cells with LSCM cathodes were tested under external potential load at temperatures between 750 degrees C and 1000 degrees C using 3% steam/Ar/4% H-2 and 3% steam/Ar, and promising polarisation impedance data were obtained in both atmospheres, especially in the gas without H-2. I-V curves from LSCM cells in 3% steam/Ar have sigmoidal shape indicative of chemical changes in the LSCM occurring in addition to electrolysis. Despite these features, considerably improved performance is found compared to Ni-based electrodes in low hydrogen conditions.

Original languageEnglish
Pages (from-to)2349-2354
Number of pages6
JournalJournal of Materials Chemistry
Volume18
DOIs
Publication statusPublished - 28 May 2008

Keywords

  • FUEL PRODUCTION
  • WIND
  • OXIDATION
  • ENERGY
  • ELECTRICITY
  • ELECTRODES
  • METHANE
  • ANODE

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