Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes

O Navarro; Steven Patrick Nolan

doi:10.1055/s-2005-918497

Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes

O Navarro, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Improved one-pot syntheses of (IPr)Pd(allyl)Cl {IPr = [N,N'-bis(2,6-diisopropylphenyl)imidazol]-2-ylidene} and (SIPr)Pd(allyl)CI {SIPr = [N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol]-2-ylidene} complexes are described. This simple method utilizes technical grade isopropanol and water as solvents, affording gram quantities of the cross-coupling pre-catalysts.

Original language	English
Pages (from-to)	366-367
Number of pages	2
Journal	Synthesis
Issue number	2
DOIs	https://doi.org/10.1055/s-2005-918497
Publication status	Published - 18 Jan 2006

Keywords

N-heterocyclic carbene
palladium
homogeneous catalysis
NUCLEOPHILIC CARBENES
(NHC)PD(ALLYL)CL NHC
STABILIZATION
ARYLATION
CATALYSTS
ALCOHOLS

Access to Document

10.1055/s-2005-918497

Cite this

@article{60cf8c1a30394ff3856af5f130444bf5,

title = "Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes",

abstract = "Improved one-pot syntheses of (IPr)Pd(allyl)Cl {IPr = [N,N'-bis(2,6-diisopropylphenyl)imidazol]-2-ylidene} and (SIPr)Pd(allyl)CI {SIPr = [N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol]-2-ylidene} complexes are described. This simple method utilizes technical grade isopropanol and water as solvents, affording gram quantities of the cross-coupling pre-catalysts.",

keywords = "N-heterocyclic carbene, palladium, homogeneous catalysis, NUCLEOPHILIC CARBENES, (NHC)PD(ALLYL)CL NHC, STABILIZATION, ARYLATION, CATALYSTS, ALCOHOLS",

author = "O Navarro and Nolan, {Steven Patrick}",

year = "2006",

month = jan,

day = "18",

doi = "10.1055/s-2005-918497",

language = "English",

pages = "366--367",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "2",

}

TY - JOUR

T1 - Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes

AU - Navarro, O

AU - Nolan, Steven Patrick

PY - 2006/1/18

Y1 - 2006/1/18

N2 - Improved one-pot syntheses of (IPr)Pd(allyl)Cl {IPr = [N,N'-bis(2,6-diisopropylphenyl)imidazol]-2-ylidene} and (SIPr)Pd(allyl)CI {SIPr = [N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol]-2-ylidene} complexes are described. This simple method utilizes technical grade isopropanol and water as solvents, affording gram quantities of the cross-coupling pre-catalysts.

AB - Improved one-pot syntheses of (IPr)Pd(allyl)Cl {IPr = [N,N'-bis(2,6-diisopropylphenyl)imidazol]-2-ylidene} and (SIPr)Pd(allyl)CI {SIPr = [N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol]-2-ylidene} complexes are described. This simple method utilizes technical grade isopropanol and water as solvents, affording gram quantities of the cross-coupling pre-catalysts.

KW - N-heterocyclic carbene

KW - palladium

KW - homogeneous catalysis

KW - NUCLEOPHILIC CARBENES

KW - (NHC)PD(ALLYL)CL NHC

KW - STABILIZATION

KW - ARYLATION

KW - CATALYSTS

KW - ALCOHOLS

UR - http://www.scopus.com/inward/record.url?scp=31544483930&partnerID=8YFLogxK

U2 - 10.1055/s-2005-918497

DO - 10.1055/s-2005-918497

M3 - Article

SN - 0039-7881

SP - 366

EP - 367

JO - Synthesis

JF - Synthesis

IS - 2

ER -

Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this