Large-amplitude molecular motions in solid metallorganic compounds. Selected X-ray diffraction and C-13 CP-MAS NMR spectroscopic investigations

W Domalewski, F G Riddell

Research output: Contribution to journalArticlepeer-review

Abstract

Representative examples of large-amplitude dynamic phenomena in various classes of solid metallorganic compounds are presented. The application of X-ray diffraction measurements and variable-temperature high-resolution NMR spectroscopy for investigation of these motions is described. Advantages and disadvantages of these methods and their complimentary character are shown.

Original languageEnglish
Pages (from-to)41-66
Number of pages28
JournalBulletin of the Polish Academy of Sciences - Chemistry
Volume47
Publication statusPublished - 1999

Keywords

  • STEREOCHEMICAL NONRIGIDITY
  • DYNAMIC PROCESSES
  • STATE NMR
  • COMPLEXES
  • ROTATION
  • DISORDER

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