Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142

Ram R. R. Prasad; Charlotte Pleass; Amber  Rigg; David Bradford Cordes; Magdalena Malgorzata Lozinska; Veselina Mihaylova Georgieva; Frank Hoffmann; Alexandra Martha Zoya Slawin; Paul Anthony Wright

doi:10.1039/D0CE01593H

Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142

Ram R. R. Prasad, Charlotte Pleass, Amber Rigg, David Bradford Cordes, Magdalena Malgorzata Lozinska, Veselina Mihaylova Georgieva, Frank Hoffmann, Alexandra Martha Zoya Slawin, Paul Anthony Wright

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Abstract

Interpenetrated multicomponent MIL-142(Sc) MOFs were synthesised using the planar tritopic (4,4’,4’’-(1,3,5-triazine-2,4,6-triyl)tribenzoate, TATB, or 4,4’,4’’-(pyridine-2,4,6-triyl)tribenzoate, PTB)) and linear ditopic (1,4-benzenedicarboxylate, BDC, or 2-amino or 2-nitro-1,4-benzenedicarboxylate (NH_2- or NO_2-BDC) linkers. Structure solution of the MIL-142(Sc)-TATB series from single crystal X-ray diffraction in space group R3 ̅m reveals regioselective ordering of bulky NO2 groups in MIL-142(Sc)-TATB-NO₂. Use of 1,3,5-benzenetribenzoate (BTB) favours instead the mesoporous Sc-BTB, the PTB analogue of which forms in the absence of BDC. The materials are highly porous: MIL-142(Sc)-TATB-BDC has a pore volume of 0.70 cm³ g^-1.

Original language	English
Number of pages	11
Journal	CrystEngComm
Early online date	8 Dec 2020
DOIs	https://doi.org/10.1039/D0CE01593H
Publication status	E-pub ahead of print - 8 Dec 2020

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Prasad-2020-Isoreticular-chemistry-of-CrystEngComm-AAM
Copyright © 2020 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D0CE01593H.
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fLEXICCS ACCOUNT P WRIGHT: Versatile Adsorption Processes for the Capture of Carbon Dioxide from Industrial Sources - FlexICCS
Wright, P. A. (PI)
EPSRC
1/09/16 → 30/04/21
Project: Standard

CCDC 2039587 - 2039591: Experimental Crystal Structure Determination
Prasad, R. R. R. (Creator), Pleass, C. (Creator), Rigg, A. L. (Creator), Cordes, D. B. (Creator), Lozinska, M. M. (Creator), Georgieva, V. M. (Creator), Hoffmann, F. (Creator), Slawin, A. M. Z. (Creator) & Wright, P. A. (Creator), Cambridge Crystallographic Data Centre, 2020
DOI: 10.5517/ccdc.csd.cc26gc46, https://dx.doi.org/10.5517/ccdc.csd.cc26gc8b and 3 more links, https://dx.doi.org/10.5517/ccdc.csd.cc26gc79, https://dx.doi.org/10.5517/ccdc.csd.cc26gc68, https://dx.doi.org/10.5517/ccdc.csd.cc26gc57 (show fewer)
Dataset
Isoreticular Chemistry of Scandium Analogues of the Multicomponent Metal-Organic Framework MIL-142 (dataset)
R R, R. P. (Creator), Pleass, C. (Creator), Rigg, A. L. (Creator), Cordes, D. B. (Creator), Lozinska, M. M. (Creator), Georgieva, V. M. (Creator), Hoffmann, F. (Creator), Slawin, A. M. Z. (Creator) & Wright, P. A. (Creator), University of St Andrews, 2020
DOI: 10.17630/536b5f75-ce3c-414b-a336-497e00280158
Dataset

File

Cite this

@article{5e2ba1bc4979437b8979439ca704dceb,

title = "Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142",

abstract = "Interpenetrated multicomponent MIL-142(Sc) MOFs were synthesised using the planar tritopic (4,4{\textquoteright},4{\textquoteright}{\textquoteright}-(1,3,5-triazine-2,4,6-triyl)tribenzoate, TATB, or 4,4{\textquoteright},4{\textquoteright}{\textquoteright}-(pyridine-2,4,6-triyl)tribenzoate, PTB)) and linear ditopic (1,4-benzenedicarboxylate, BDC, or 2-amino or 2-nitro-1,4-benzenedicarboxylate (NH2- or NO2-BDC) linkers. Structure solution of the MIL-142(Sc)-TATB series from single crystal X-ray diffraction in space group R3 ̅m reveals regioselective ordering of bulky NO2 groups in MIL-142(Sc)-TATB-NO2. Use of 1,3,5-benzenetribenzoate (BTB) favours instead the mesoporous Sc-BTB, the PTB analogue of which forms in the absence of BDC. The materials are highly porous: MIL-142(Sc)-TATB-BDC has a pore volume of 0.70 cm3 g-1. ",

author = "Prasad, {Ram R. R.} and Charlotte Pleass and Amber Rigg and Cordes, {David Bradford} and Lozinska, {Magdalena Malgorzata} and Georgieva, {Veselina Mihaylova} and Frank Hoffmann and Slawin, {Alexandra Martha Zoya} and Wright, {Paul Anthony}",

note = "RRRP and PAW thank the Engineering and Physical Sciences Research Council (EPSRC) and CRITICAT Centre for Doctoral Training for Financial Support [PhD studentship to RRRP; EP/L016419/1]. MML and PAW would also like to thank EPSRC for FLEXICCS grant (Versatile Adsorption Process for the Capture of Carbon Dioxide from Industrial Sources; EP/N024613/1). The research data supporting this publication can be accessed at: https://doi.org/10.17630/536b5f75-ce3c-414b-a336-497e00280158.56",

year = "2020",

month = dec,

day = "8",

doi = "10.1039/D0CE01593H",

language = "English",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "ROYAL SOC CHEMISTRY",

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TY - JOUR

T1 - Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142

AU - Prasad, Ram R. R.

AU - Pleass, Charlotte

AU - Rigg, Amber

AU - Cordes, David Bradford

AU - Lozinska, Magdalena Malgorzata

AU - Georgieva, Veselina Mihaylova

AU - Hoffmann, Frank

AU - Slawin, Alexandra Martha Zoya

AU - Wright, Paul Anthony

N1 - RRRP and PAW thank the Engineering and Physical Sciences Research Council (EPSRC) and CRITICAT Centre for Doctoral Training for Financial Support [PhD studentship to RRRP; EP/L016419/1]. MML and PAW would also like to thank EPSRC for FLEXICCS grant (Versatile Adsorption Process for the Capture of Carbon Dioxide from Industrial Sources; EP/N024613/1). The research data supporting this publication can be accessed at: https://doi.org/10.17630/536b5f75-ce3c-414b-a336-497e00280158.56

PY - 2020/12/8

Y1 - 2020/12/8

N2 - Interpenetrated multicomponent MIL-142(Sc) MOFs were synthesised using the planar tritopic (4,4’,4’’-(1,3,5-triazine-2,4,6-triyl)tribenzoate, TATB, or 4,4’,4’’-(pyridine-2,4,6-triyl)tribenzoate, PTB)) and linear ditopic (1,4-benzenedicarboxylate, BDC, or 2-amino or 2-nitro-1,4-benzenedicarboxylate (NH2- or NO2-BDC) linkers. Structure solution of the MIL-142(Sc)-TATB series from single crystal X-ray diffraction in space group R3 ̅m reveals regioselective ordering of bulky NO2 groups in MIL-142(Sc)-TATB-NO2. Use of 1,3,5-benzenetribenzoate (BTB) favours instead the mesoporous Sc-BTB, the PTB analogue of which forms in the absence of BDC. The materials are highly porous: MIL-142(Sc)-TATB-BDC has a pore volume of 0.70 cm3 g-1.

AB - Interpenetrated multicomponent MIL-142(Sc) MOFs were synthesised using the planar tritopic (4,4’,4’’-(1,3,5-triazine-2,4,6-triyl)tribenzoate, TATB, or 4,4’,4’’-(pyridine-2,4,6-triyl)tribenzoate, PTB)) and linear ditopic (1,4-benzenedicarboxylate, BDC, or 2-amino or 2-nitro-1,4-benzenedicarboxylate (NH2- or NO2-BDC) linkers. Structure solution of the MIL-142(Sc)-TATB series from single crystal X-ray diffraction in space group R3 ̅m reveals regioselective ordering of bulky NO2 groups in MIL-142(Sc)-TATB-NO2. Use of 1,3,5-benzenetribenzoate (BTB) favours instead the mesoporous Sc-BTB, the PTB analogue of which forms in the absence of BDC. The materials are highly porous: MIL-142(Sc)-TATB-BDC has a pore volume of 0.70 cm3 g-1.

U2 - 10.1039/D0CE01593H

DO - 10.1039/D0CE01593H

M3 - Article

SN - 1466-8033

JO - CrystEngComm

JF - CrystEngComm

ER -

Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142

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fLEXICCS ACCOUNT P WRIGHT: Versatile Adsorption Processes for the Capture of Carbon Dioxide from Industrial Sources - FlexICCS

Datasets

CCDC 2039587 - 2039591: Experimental Crystal Structure Determination

Isoreticular Chemistry of Scandium Analogues of the Multicomponent Metal-Organic Framework MIL-142 (dataset)

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