Isophthalic Acid: A Basis for Highly Ordered Monolayers

Izabela Cebula; Cai Shen; Manfred Buck

doi:10.1002/anie.201002082

Isophthalic Acid: A Basis for Highly Ordered Monolayers

Izabela Cebula, Cai Shen, Manfred Buck

Research output: Contribution to journal › Article › peer-review

Abstract

Standing on their own two feet: Underpotential deposition of Cu on Au(111) yields a surface onto which 1,3-benzenedicarboxylic acid (IPA) and 1,3,5-benzenetricarboxylic acid (TMA) adsorb in a bipodal configuration. Both molecules form highly crystalline isostructural monolayers, thus demonstrating the potential of the IPA moiety as tecton for self-assembled monolayers. A thin film of a Cu–TMA coordination polymer was grown on a patterned TMA monolayer.

Original language	English
Pages (from-to)	6220-6223
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	49
Issue number	35
DOIs	https://doi.org/10.1002/anie.201002082
Publication status	Published - 16 Aug 2010

Keywords

coordination chemistry
electrochemistry
self-assembled monolayers
surface chemistry
SELF-ASSEMBLED MONOLAYERS
ORGANIC COORDINATION NETWORKS
LIQUID-SOLID INTERFACE
TRIMESIC ACID
MOLECULAR CRYSTALLIZATION
METAL-SURFACE
HYDROGEN
COPPER
REORIENTATION
ADSORPTION

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title = "Isophthalic Acid: A Basis for Highly Ordered Monolayers",

abstract = "Standing on their own two feet: Underpotential deposition of Cu on Au(111) yields a surface onto which 1,3-benzenedicarboxylic acid (IPA) and 1,3,5-benzenetricarboxylic acid (TMA) adsorb in a bipodal configuration. Both molecules form highly crystalline isostructural monolayers, thus demonstrating the potential of the IPA moiety as tecton for self-assembled monolayers. A thin film of a Cu–TMA coordination polymer was grown on a patterned TMA monolayer.",

keywords = "coordination chemistry, electrochemistry, self-assembled monolayers, surface chemistry, SELF-ASSEMBLED MONOLAYERS, ORGANIC COORDINATION NETWORKS, LIQUID-SOLID INTERFACE, TRIMESIC ACID, MOLECULAR CRYSTALLIZATION, METAL-SURFACE, HYDROGEN, COPPER, REORIENTATION, ADSORPTION",

author = "Izabela Cebula and Cai Shen and Manfred Buck",

year = "2010",

month = aug,

day = "16",

doi = "10.1002/anie.201002082",

language = "English",

volume = "49",

pages = "6220--6223",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons, Ltd",

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TY - JOUR

T1 - Isophthalic Acid

T2 - A Basis for Highly Ordered Monolayers

AU - Cebula, Izabela

AU - Shen, Cai

AU - Buck, Manfred

PY - 2010/8/16

Y1 - 2010/8/16

N2 - Standing on their own two feet: Underpotential deposition of Cu on Au(111) yields a surface onto which 1,3-benzenedicarboxylic acid (IPA) and 1,3,5-benzenetricarboxylic acid (TMA) adsorb in a bipodal configuration. Both molecules form highly crystalline isostructural monolayers, thus demonstrating the potential of the IPA moiety as tecton for self-assembled monolayers. A thin film of a Cu–TMA coordination polymer was grown on a patterned TMA monolayer.

AB - Standing on their own two feet: Underpotential deposition of Cu on Au(111) yields a surface onto which 1,3-benzenedicarboxylic acid (IPA) and 1,3,5-benzenetricarboxylic acid (TMA) adsorb in a bipodal configuration. Both molecules form highly crystalline isostructural monolayers, thus demonstrating the potential of the IPA moiety as tecton for self-assembled monolayers. A thin film of a Cu–TMA coordination polymer was grown on a patterned TMA monolayer.

KW - coordination chemistry

KW - electrochemistry

KW - self-assembled monolayers

KW - surface chemistry

KW - SELF-ASSEMBLED MONOLAYERS

KW - ORGANIC COORDINATION NETWORKS

KW - LIQUID-SOLID INTERFACE

KW - TRIMESIC ACID

KW - MOLECULAR CRYSTALLIZATION

KW - METAL-SURFACE

KW - HYDROGEN

KW - COPPER

KW - REORIENTATION

KW - ADSORPTION

U2 - 10.1002/anie.201002082

DO - 10.1002/anie.201002082

M3 - Article

SN - 1433-7851

VL - 49

SP - 6220

EP - 6223

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 35

ER -

Isophthalic Acid: A Basis for Highly Ordered Monolayers

Abstract

Keywords

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