IRON(III)CHLORIDE OXIDATION OF TRICARBONYL(VINYLKETENE)IRON(0)-ALKYNE ADDUCTS

S P  SABERI; M M  SALTER; A M Z  SLAWIN; S E  THOMAS; D J  WILLIAMS

IRON(III)CHLORIDE OXIDATION OF TRICARBONYL(VINYLKETENE)IRON(0)-ALKYNE ADDUCTS

S P SABERI
, M M SALTER
, A M Z SLAWIN
, S E THOMAS
, D J WILLIAMS

Research output: Contribution to journal › Article › peer-review

Abstract

Oxidation of the adducts formed from tricarbonyl (vinylketene) iron(o) complexes and alkynes by iron(lll) chloride in methanol/water leads to the replacement of the tricarbonyliron(o) unit with an oxygen atom derived from the water. This pathway to furan-3(2H)-ones requires the presence of an electron-withdrawing substituent on carbon-2 of the vinylketene-alkyne adduct. Data used to assign the structures of some of the vinylketene-alkyne adducts used in this study included an X-ray crystal structure analysis of the unusual lactone complex 5c.

Original language	English
Pages (from-to)	167-171
Number of pages	5
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	2
Publication status	Published - 21 Jan 1994

Keywords

COMPLEXES

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title = "IRON(III)CHLORIDE OXIDATION OF TRICARBONYL(VINYLKETENE)IRON(0)-ALKYNE ADDUCTS",

abstract = "Oxidation of the adducts formed from tricarbonyl (vinylketene) iron(o) complexes and alkynes by iron(lll) chloride in methanol/water leads to the replacement of the tricarbonyliron(o) unit with an oxygen atom derived from the water. This pathway to furan-3(2H)-ones requires the presence of an electron-withdrawing substituent on carbon-2 of the vinylketene-alkyne adduct. Data used to assign the structures of some of the vinylketene-alkyne adducts used in this study included an X-ray crystal structure analysis of the unusual lactone complex 5c.",

keywords = "COMPLEXES",

author = "SABERI, \{S P\} and SALTER, \{M M\} and SLAWIN, \{A M Z\} and THOMAS, \{S E\} and WILLIAMS, \{D J\}",

year = "1994",

month = jan,

day = "21",

language = "English",

pages = "167--171",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "0300-922X",

publisher = "Chemical Society",

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TY - JOUR

T1 - IRON(III)CHLORIDE OXIDATION OF TRICARBONYL(VINYLKETENE)IRON(0)-ALKYNE ADDUCTS

AU - SABERI, S P

AU - SALTER, M M

AU - SLAWIN, A M Z

AU - THOMAS, S E

AU - WILLIAMS, D J

PY - 1994/1/21

Y1 - 1994/1/21

N2 - Oxidation of the adducts formed from tricarbonyl (vinylketene) iron(o) complexes and alkynes by iron(lll) chloride in methanol/water leads to the replacement of the tricarbonyliron(o) unit with an oxygen atom derived from the water. This pathway to furan-3(2H)-ones requires the presence of an electron-withdrawing substituent on carbon-2 of the vinylketene-alkyne adduct. Data used to assign the structures of some of the vinylketene-alkyne adducts used in this study included an X-ray crystal structure analysis of the unusual lactone complex 5c.

AB - Oxidation of the adducts formed from tricarbonyl (vinylketene) iron(o) complexes and alkynes by iron(lll) chloride in methanol/water leads to the replacement of the tricarbonyliron(o) unit with an oxygen atom derived from the water. This pathway to furan-3(2H)-ones requires the presence of an electron-withdrawing substituent on carbon-2 of the vinylketene-alkyne adduct. Data used to assign the structures of some of the vinylketene-alkyne adducts used in this study included an X-ray crystal structure analysis of the unusual lactone complex 5c.

KW - COMPLEXES

M3 - Article

SN - 0300-922X

SP - 167

EP - 171

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 2

ER -

IRON(III)CHLORIDE OXIDATION OF TRICARBONYL(VINYLKETENE)IRON(0)-ALKYNE ADDUCTS

Abstract

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