Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones” Nelson, D.J., Fernandez-Salas, J.A., Truscott, B.J. and Nolan, S.P. Org. Biomol, Chem., 2014, 12, 6672-6676.

David James Nelson, Jose Antonio Fernandez Salas, Byron Truscott, Steven Patrick Nolan

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Abstract

The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1–1.5 h) with microwave heating, in the absence of additives.
Original languageEnglish
Pages (from-to)6672-6676
Number of pages5
JournalOrganic & Biomolecular Chemistry
Volume12
Early online date15 Jul 2014
DOIs
Publication statusPublished - 2014

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