[(IPr)Pd(0)] species: a versatile, well-defined catalyst precursor for cross coupling reactions

NM Scott; O Navarro; O Briel; Steven Patrick Nolan

[(IPr)Pd(0)] species: a versatile, well-defined catalyst precursor for cross coupling reactions

NM Scott, O Navarro, O Briel, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.

Original language	English
Pages (from-to)	10-14
Number of pages	5
Journal	Chimica Oggi-Chemistry Today
Volume	23
Issue number	4
Publication status	Published - Jul 2005

Keywords

N-HETEROCYCLIC CARBENE
OLEFIN METATHESIS CATALYSTS
ACTIVE PALLADIUM CATALYSTS
ARYL CHLORIDES
ARYLBORONIC ACIDS
ALPHA-ARYLATION
BOND FORMATION
COMPLEXES BEARING
C-N
BROMIDES

Cite this

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title = "[(IPr)Pd(0)] species: a versatile, well-defined catalyst precursor for cross coupling reactions",

abstract = "The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.",

keywords = "N-HETEROCYCLIC CARBENE, OLEFIN METATHESIS CATALYSTS, ACTIVE PALLADIUM CATALYSTS, ARYL CHLORIDES, ARYLBORONIC ACIDS, ALPHA-ARYLATION, BOND FORMATION, COMPLEXES BEARING, C-N, BROMIDES",

author = "NM Scott and O Navarro and O Briel and Nolan, {Steven Patrick}",

year = "2005",

month = jul,

language = "English",

volume = "23",

pages = "10--14",

journal = "Chimica Oggi-Chemistry Today",

issn = "0392-839X",

publisher = "TeknoScienze",

number = "4",

}

TY - JOUR

T1 - [(IPr)Pd(0)] species: a versatile, well-defined catalyst precursor for cross coupling reactions

AU - Scott, NM

AU - Navarro, O

AU - Briel, O

AU - Nolan, Steven Patrick

PY - 2005/7

Y1 - 2005/7

N2 - The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.

AB - The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.

KW - N-HETEROCYCLIC CARBENE

KW - OLEFIN METATHESIS CATALYSTS

KW - ACTIVE PALLADIUM CATALYSTS

KW - ARYL CHLORIDES

KW - ARYLBORONIC ACIDS

KW - ALPHA-ARYLATION

KW - BOND FORMATION

KW - COMPLEXES BEARING

KW - C-N

KW - BROMIDES

UR - http://www.scopus.com/inward/record.url?scp=25444486157&partnerID=8YFLogxK

M3 - Article

SN - 0392-839X

VL - 23

SP - 10

EP - 14

JO - Chimica Oggi-Chemistry Today

JF - Chimica Oggi-Chemistry Today

IS - 4

ER -

[(IPr)Pd(0)] species: a versatile, well-defined catalyst precursor for cross coupling reactions

Abstract

Keywords

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