Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

Emily R. Parnham; Russell E. Morris

doi:10.1021/ar700025k

Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

Research output: Contribution to journal › Review article › peer-review

Abstract

Ionothermal synthesis, the use of ionic liquids as both solvent and template (structure -directing agent), has been used to prepare zeolites and inorganic-organic hybrids such as metal-organic frameworks. The underlying properties of the ionothermal method are discussed, and it is compared with traditional hydrothermal preparative methods. The materials resulting from ionothermal synthesis are described, and any structural features that can be related to the ionic liquid used as the solvent are discussed. Future areas of potential interest are also considered.

Original language	English
Pages (from-to)	1005-1013
Number of pages	9
Journal	Accounts of Chemical Research
Volume	40
DOIs	https://doi.org/10.1021/ar700025k
Publication status	Published - Oct 2007

Keywords

ALUMINOPHOSPHATE MOLECULAR-SIEVES
IONIC LIQUIDS
COORDINATION POLYMER
HYDROTHERMAL SYNTHESIS
CHOLINE CHLORIDE/UREA
GALLIUM PHOSPHATE
CRYSTAL-STRUCTURE
SOLVENT
TEMPLATE
WATER

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title = "Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids",

abstract = "Ionothermal synthesis, the use of ionic liquids as both solvent and template (structure -directing agent), has been used to prepare zeolites and inorganic-organic hybrids such as metal-organic frameworks. The underlying properties of the ionothermal method are discussed, and it is compared with traditional hydrothermal preparative methods. The materials resulting from ionothermal synthesis are described, and any structural features that can be related to the ionic liquid used as the solvent are discussed. Future areas of potential interest are also considered.",

keywords = "ALUMINOPHOSPHATE MOLECULAR-SIEVES, IONIC LIQUIDS, COORDINATION POLYMER, HYDROTHERMAL SYNTHESIS, CHOLINE CHLORIDE/UREA, GALLIUM PHOSPHATE, CRYSTAL-STRUCTURE, SOLVENT, TEMPLATE, WATER",

author = "Parnham, {Emily R.} and Morris, {Russell E.}",

year = "2007",

month = oct,

doi = "10.1021/ar700025k",

language = "English",

volume = "40",

pages = "1005--1013",

journal = "Accounts of Chemical Research",

issn = "0001-4842",

publisher = "American Chemical Society (ACS)",

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T1 - Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

AU - Parnham, Emily R.

AU - Morris, Russell E.

PY - 2007/10

Y1 - 2007/10

N2 - Ionothermal synthesis, the use of ionic liquids as both solvent and template (structure -directing agent), has been used to prepare zeolites and inorganic-organic hybrids such as metal-organic frameworks. The underlying properties of the ionothermal method are discussed, and it is compared with traditional hydrothermal preparative methods. The materials resulting from ionothermal synthesis are described, and any structural features that can be related to the ionic liquid used as the solvent are discussed. Future areas of potential interest are also considered.

AB - Ionothermal synthesis, the use of ionic liquids as both solvent and template (structure -directing agent), has been used to prepare zeolites and inorganic-organic hybrids such as metal-organic frameworks. The underlying properties of the ionothermal method are discussed, and it is compared with traditional hydrothermal preparative methods. The materials resulting from ionothermal synthesis are described, and any structural features that can be related to the ionic liquid used as the solvent are discussed. Future areas of potential interest are also considered.

KW - ALUMINOPHOSPHATE MOLECULAR-SIEVES

KW - IONIC LIQUIDS

KW - COORDINATION POLYMER

KW - HYDROTHERMAL SYNTHESIS

KW - CHOLINE CHLORIDE/UREA

KW - GALLIUM PHOSPHATE

KW - CRYSTAL-STRUCTURE

KW - SOLVENT

KW - TEMPLATE

KW - WATER

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U2 - 10.1021/ar700025k

DO - 10.1021/ar700025k

M3 - Review article

SN - 0001-4842

VL - 40

SP - 1005

EP - 1013

JO - Accounts of Chemical Research

JF - Accounts of Chemical Research

ER -

Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

Abstract

Keywords

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