Ionothermal synthesis of two novel metal organophosphonates

Peter J. Byrne; David S. Wragg; John E. Warren; Russell E. Morris

doi:10.1039/b813731e

Ionothermal synthesis of two novel metal organophosphonates

Peter J. Byrne, David S. Wragg, John E. Warren, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel metal phosphonates, Al5F(C4H9PO3)(6)(OH)(2)(C4N2H6)(2) 1 and Ga4F2(C4H9PO3)(8)H-5 center dot(C7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered.

Original language	English
Pages (from-to)	795-799
Number of pages	5
Journal	Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/b813731e
Publication status	Published - 2009

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title = "Ionothermal synthesis of two novel metal organophosphonates",

abstract = "Two novel metal phosphonates, Al5F(C4H9PO3)(6)(OH)(2)(C4N2H6)(2) 1 and Ga4F2(C4H9PO3)(8)H-5 center dot(C7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered.",

author = "Byrne, {Peter J.} and Wragg, {David S.} and Warren, {John E.} and Morris, {Russell E.}",

year = "2009",

doi = "10.1039/b813731e",

language = "English",

pages = "795--799",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "5",

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T1 - Ionothermal synthesis of two novel metal organophosphonates

AU - Byrne, Peter J.

AU - Wragg, David S.

AU - Warren, John E.

AU - Morris, Russell E.

PY - 2009

Y1 - 2009

N2 - Two novel metal phosphonates, Al5F(C4H9PO3)(6)(OH)(2)(C4N2H6)(2) 1 and Ga4F2(C4H9PO3)(8)H-5 center dot(C7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered.

AB - Two novel metal phosphonates, Al5F(C4H9PO3)(6)(OH)(2)(C4N2H6)(2) 1 and Ga4F2(C4H9PO3)(8)H-5 center dot(C7N2H11) 2 have been prepared using an ionothermal approach and their structures solved using single-crystal X-ray diffraction. In 1, the breakdown of the ionic liquid solvent has occurred and a fragment of the cation coordinates to the aluminium in the structure. In 2, the ionic liquid cation acts as the template and is occluded. Compound 1 is a chain structure while compound 2 is molecular, unlike the vast majority of hydrothermally synthesised phosphonates, which are layered.

U2 - 10.1039/b813731e

DO - 10.1039/b813731e

M3 - Article

SN - 1477-9226

SP - 795

EP - 799

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Ionothermal synthesis of two novel metal organophosphonates

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