Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands

Zeric Hulvey; David S. Wragg; Zhuojia Lin; Russell E. Morris; Anthony K. Cheetham

doi:10.1039/b817542j

Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands

Zeric Hulvey, David S. Wragg, Zhuojia Lin, Russell E. Morris, Anthony K. Cheetham

Research output: Contribution to journal › Article › peer-review

Abstract

Two new hybrid inorganic-organic frameworks containing perfluorinated dicarboxylate ligands have been synthesized ionothermally from a mixture of 1-ethyl-3- methylimidazolium bromide (emim-Br), and triflimide (emim-Tf2N). The cobalt(II) tetrafluorosuccinate, [emim](2)[Co(H2O)(2)(O2CCF2CF2CO2)(2)] (1), is a two-dimensional coordination polymer containing anionic framework layers separated by emim cations. When hexafluoroglutaric acid is used in similar reactions, [emim](2)[Co-3(O2CCF2CF2CF2CO2)(4)(H2O)(4)] (2) forms. Like 1, this phase contains anionic layers of cobalt and the fluorinated carboxylate separated by emim cations. These new phases represent the first examples of ionothermally synthesized materials using perfluorinated aliphatic carboxylates.

Original language	English
Pages (from-to)	1131-1135
Number of pages	5
Journal	Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/b817542j
Publication status	Published - 2009

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title = "Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands",

abstract = "Two new hybrid inorganic-organic frameworks containing perfluorinated dicarboxylate ligands have been synthesized ionothermally from a mixture of 1-ethyl-3- methylimidazolium bromide (emim-Br), and triflimide (emim-Tf2N). The cobalt(II) tetrafluorosuccinate, [emim](2)[Co(H2O)(2)(O2CCF2CF2CO2)(2)] (1), is a two-dimensional coordination polymer containing anionic framework layers separated by emim cations. When hexafluoroglutaric acid is used in similar reactions, [emim](2)[Co-3(O2CCF2CF2CF2CO2)(4)(H2O)(4)] (2) forms. Like 1, this phase contains anionic layers of cobalt and the fluorinated carboxylate separated by emim cations. These new phases represent the first examples of ionothermally synthesized materials using perfluorinated aliphatic carboxylates.",

author = "Zeric Hulvey and Wragg, {David S.} and Zhuojia Lin and Morris, {Russell E.} and Cheetham, {Anthony K.}",

year = "2009",

doi = "10.1039/b817542j",

language = "English",

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journal = "Dalton Transactions",

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T1 - Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands

AU - Hulvey, Zeric

AU - Wragg, David S.

AU - Lin, Zhuojia

AU - Morris, Russell E.

AU - Cheetham, Anthony K.

PY - 2009

Y1 - 2009

N2 - Two new hybrid inorganic-organic frameworks containing perfluorinated dicarboxylate ligands have been synthesized ionothermally from a mixture of 1-ethyl-3- methylimidazolium bromide (emim-Br), and triflimide (emim-Tf2N). The cobalt(II) tetrafluorosuccinate, [emim](2)[Co(H2O)(2)(O2CCF2CF2CO2)(2)] (1), is a two-dimensional coordination polymer containing anionic framework layers separated by emim cations. When hexafluoroglutaric acid is used in similar reactions, [emim](2)[Co-3(O2CCF2CF2CF2CO2)(4)(H2O)(4)] (2) forms. Like 1, this phase contains anionic layers of cobalt and the fluorinated carboxylate separated by emim cations. These new phases represent the first examples of ionothermally synthesized materials using perfluorinated aliphatic carboxylates.

AB - Two new hybrid inorganic-organic frameworks containing perfluorinated dicarboxylate ligands have been synthesized ionothermally from a mixture of 1-ethyl-3- methylimidazolium bromide (emim-Br), and triflimide (emim-Tf2N). The cobalt(II) tetrafluorosuccinate, [emim](2)[Co(H2O)(2)(O2CCF2CF2CO2)(2)] (1), is a two-dimensional coordination polymer containing anionic framework layers separated by emim cations. When hexafluoroglutaric acid is used in similar reactions, [emim](2)[Co-3(O2CCF2CF2CF2CO2)(4)(H2O)(4)] (2) forms. Like 1, this phase contains anionic layers of cobalt and the fluorinated carboxylate separated by emim cations. These new phases represent the first examples of ionothermally synthesized materials using perfluorinated aliphatic carboxylates.

U2 - 10.1039/b817542j

DO - 10.1039/b817542j

M3 - Article

SN - 1477-9226

SP - 1131

EP - 1135

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands

Abstract

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