Ionothermal synthesis and crystal structures of metal phosphate chains

David S. Wragg; Benjamin Le Ouay; Andrew M. Beale; Matthew G. O'Brien; Alexandra M. Z. Slawin; John E. Warren; Timothy J. Prior; Russell E. Morris

doi:10.1016/j.jssc.2010.05.002

Ionothermal synthesis and crystal structures of metal phosphate chains

David S. Wragg, Benjamin Le Ouay, Andrew M. Beale, Matthew G. O'Brien, Alexandra M. Z. Slawin, John E. Warren, Timothy J. Prior, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. (C) 2010 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	1625-1631
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	183
Issue number	7
Early online date	11 May 2010
DOIs	https://doi.org/10.1016/j.jssc.2010.05.002
Publication status	Published - Jul 2010

Keywords

Ionothermal synthesis
X-ray diffraction
Crystal structure
Chain
TEMPERATURE IONIC LIQUIDS
OPEN-FRAMEWORK STRUCTURES
GALLIUM PHOSPHATE
MOLECULAR-SIEVES
ORGANIC FRAMEWORKS
INORGANIC SOLIDS
ALUMINOPHOSPHATE
GALLOPHOSPHATE
SOLVENTS
COMPLEXES

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10.1016/j.jssc.2010.05.002

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues
Morris, R. E. (PI)
EPSRC
1/07/05 → 31/12/08
Project: Standard

Cite this

@article{e1e2772f8a9240f8b4ea6bd3c2301367,

title = "Ionothermal synthesis and crystal structures of metal phosphate chains",

abstract = "We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. (C) 2010 Elsevier Inc. All rights reserved.",

keywords = "Ionothermal synthesis, X-ray diffraction, Crystal structure, Chain, TEMPERATURE IONIC LIQUIDS, OPEN-FRAMEWORK STRUCTURES, GALLIUM PHOSPHATE, MOLECULAR-SIEVES, ORGANIC FRAMEWORKS, INORGANIC SOLIDS, ALUMINOPHOSPHATE, GALLOPHOSPHATE, SOLVENTS, COMPLEXES",

author = "Wragg, {David S.} and {Le Ouay}, Benjamin and Beale, {Andrew M.} and O'Brien, {Matthew G.} and Slawin, {Alexandra M. Z.} and Warren, {John E.} and Prior, {Timothy J.} and Morris, {Russell E.}",

year = "2010",

month = jul,

doi = "10.1016/j.jssc.2010.05.002",

language = "English",

volume = "183",

pages = "1625--1631",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press/Elsevier ",

number = "7",

}

TY - JOUR

T1 - Ionothermal synthesis and crystal structures of metal phosphate chains

AU - Wragg, David S.

AU - Le Ouay, Benjamin

AU - Beale, Andrew M.

AU - O'Brien, Matthew G.

AU - Slawin, Alexandra M. Z.

AU - Warren, John E.

AU - Prior, Timothy J.

AU - Morris, Russell E.

PY - 2010/7

Y1 - 2010/7

N2 - We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. (C) 2010 Elsevier Inc. All rights reserved.

AB - We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid. (C) 2010 Elsevier Inc. All rights reserved.

KW - Ionothermal synthesis

KW - X-ray diffraction

KW - Crystal structure

KW - Chain

KW - TEMPERATURE IONIC LIQUIDS

KW - OPEN-FRAMEWORK STRUCTURES

KW - GALLIUM PHOSPHATE

KW - MOLECULAR-SIEVES

KW - ORGANIC FRAMEWORKS

KW - INORGANIC SOLIDS

KW - ALUMINOPHOSPHATE

KW - GALLOPHOSPHATE

KW - SOLVENTS

KW - COMPLEXES

U2 - 10.1016/j.jssc.2010.05.002

DO - 10.1016/j.jssc.2010.05.002

M3 - Article

SN - 0022-4596

VL - 183

SP - 1625

EP - 1631

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 7

ER -

Ionothermal synthesis and crystal structures of metal phosphate chains

Abstract

Keywords

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Projects

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues

Cite this