Ionic liquids: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher alpha-olefins with cationic Ni complexes

P Wasserscheid; C M Gordon; C Hilgers; Mark James Muldoon; I R Dunkin

doi:10.1039/b101400p

Ionic liquids: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher alpha-olefins with cationic Ni complexes

P Wasserscheid, C M Gordon, C Hilgers, Mark James Muldoon, I R Dunkin

School of Chemistry

Research output: Contribution to journal › Article › peer-review

177 Citations (Scopus)

Abstract

Ethylene oligomerisation in ionic liquids gives predominately alk-1-ene products with better reactivity and selectivity than in conventional solvents; turnover frequencies are correlated with polarity data obtained using solvatochromic dyes.

Original language	English
Pages (from-to)	1186-1187
Number of pages	2
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/b101400p
Publication status	Published - Jun 2001

Keywords

TEMPERATURE MOLTEN-SALTS
CATALYTIC DIMERIZATION
NICKEL-COMPLEXES
INDICATORS

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10.1039/b101400p

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title = "Ionic liquids: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher alpha-olefins with cationic Ni complexes",

abstract = "Ethylene oligomerisation in ionic liquids gives predominately alk-1-ene products with better reactivity and selectivity than in conventional solvents; turnover frequencies are correlated with polarity data obtained using solvatochromic dyes.",

keywords = "TEMPERATURE MOLTEN-SALTS, CATALYTIC DIMERIZATION, NICKEL-COMPLEXES, INDICATORS",

author = "P Wasserscheid and Gordon, {C M} and C Hilgers and Muldoon, {Mark James} and Dunkin, {I R}",

year = "2001",

month = jun,

doi = "10.1039/b101400p",

language = "English",

pages = "1186--1187",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Ionic liquids: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher alpha-olefins with cationic Ni complexes

AU - Wasserscheid, P

AU - Gordon, C M

AU - Hilgers, C

AU - Muldoon, Mark James

AU - Dunkin, I R

PY - 2001/6

Y1 - 2001/6

N2 - Ethylene oligomerisation in ionic liquids gives predominately alk-1-ene products with better reactivity and selectivity than in conventional solvents; turnover frequencies are correlated with polarity data obtained using solvatochromic dyes.

AB - Ethylene oligomerisation in ionic liquids gives predominately alk-1-ene products with better reactivity and selectivity than in conventional solvents; turnover frequencies are correlated with polarity data obtained using solvatochromic dyes.

KW - TEMPERATURE MOLTEN-SALTS

KW - CATALYTIC DIMERIZATION

KW - NICKEL-COMPLEXES

KW - INDICATORS

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UR - http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=b101400p&JournalCode=CC

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DO - 10.1039/b101400p

M3 - Article

SN - 1359-7345

SP - 1186

EP - 1187

JO - Chemical Communications

JF - Chemical Communications

ER -

Ionic liquids: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher alpha-olefins with cationic Ni complexes

Abstract

Keywords

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