INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]

P F  KELLY; A M Z  SLAWIN; D J  WILLIAMS; J D  WOOLLINS

INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]

P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journal › Article › peer-review

Abstract

S4N4 reacts with [PPh4]2[Pd2Cl6] (1) in CH2Cl2 to give a mixture of [PPh4]2[Pd2(mu-S2N2)Cl6] (2) and [PPh4]2[Pd2(mu-S3N2)Cl4] (3). X-ray crystallography reveals (2) to contain neutral S2N2 as a bridging ligand whilst (3) constitutes only the second example of a complex of the bridging S3N2(2-) ligand.

Original language	English
Pages (from-to)	2337-2340
Number of pages	4
Journal	Polyhedron
Volume	10
Issue number	19
Publication status	Published - 1991

Keywords

ROOM-TEMPERATURE
S2N2
DERIVATIVES
COMPLEXES
CLEAVAGE

Cite this

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title = "INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]",

abstract = "S4N4 reacts with [PPh4]2[Pd2Cl6] (1) in CH2Cl2 to give a mixture of [PPh4]2[Pd2(mu-S2N2)Cl6] (2) and [PPh4]2[Pd2(mu-S3N2)Cl4] (3). X-ray crystallography reveals (2) to contain neutral S2N2 as a bridging ligand whilst (3) constitutes only the second example of a complex of the bridging S3N2(2-) ligand.",

keywords = "ROOM-TEMPERATURE, S2N2, DERIVATIVES, COMPLEXES, CLEAVAGE",

author = "KELLY, \{P F\} and SLAWIN, \{A M Z\} and WILLIAMS, \{D J\} and WOOLLINS, \{J D\}",

year = "1991",

language = "English",

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pages = "2337--2340",

journal = "Polyhedron",

issn = "0277-5387",

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number = "19",

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T1 - INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]

AU - KELLY, P F

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WOOLLINS, J D

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N2 - S4N4 reacts with [PPh4]2[Pd2Cl6] (1) in CH2Cl2 to give a mixture of [PPh4]2[Pd2(mu-S2N2)Cl6] (2) and [PPh4]2[Pd2(mu-S3N2)Cl4] (3). X-ray crystallography reveals (2) to contain neutral S2N2 as a bridging ligand whilst (3) constitutes only the second example of a complex of the bridging S3N2(2-) ligand.

AB - S4N4 reacts with [PPh4]2[Pd2Cl6] (1) in CH2Cl2 to give a mixture of [PPh4]2[Pd2(mu-S2N2)Cl6] (2) and [PPh4]2[Pd2(mu-S3N2)Cl4] (3). X-ray crystallography reveals (2) to contain neutral S2N2 as a bridging ligand whilst (3) constitutes only the second example of a complex of the bridging S3N2(2-) ligand.

KW - ROOM-TEMPERATURE

KW - S2N2

KW - DERIVATIVES

KW - COMPLEXES

KW - CLEAVAGE

UR - https://www.scopus.com/pages/publications/0344485777

M3 - Article

SN - 0277-5387

VL - 10

SP - 2337

EP - 2340

JO - Polyhedron

JF - Polyhedron

IS - 19

ER -

INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]

Abstract

Keywords

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