INVESTIGATIONS INTO THE REACTION OF S4N4 WITH [PPH4]2[PD2CL6] - THE X-RAY CRYSTAL-STRUCTURES OF [PPH4]2[PD2(MU-S2N2)CL6] AND [PPH4][PD2(MU-S3N2)CL4]

P F KELLY, A M Z SLAWIN, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

S4N4 reacts with [PPh4]2[Pd2Cl6] (1) in CH2Cl2 to give a mixture of [PPh4]2[Pd2(mu-S2N2)Cl6] (2) and [PPh4]2[Pd2(mu-S3N2)Cl4] (3). X-ray crystallography reveals (2) to contain neutral S2N2 as a bridging ligand whilst (3) constitutes only the second example of a complex of the bridging S3N2(2-) ligand.

Original languageEnglish
Pages (from-to)2337-2340
Number of pages4
JournalPolyhedron
Volume10
Issue number19
Publication statusPublished - 1991

Keywords

  • ROOM-TEMPERATURE
  • S2N2
  • DERIVATIVES
  • COMPLEXES
  • CLEAVAGE

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