Intramolecular Diels-Alder reactions of trienes tethered with an ether linkage

P J Ainsworth, D Craig, J C Reader, A M Z Slawin, A J P White, D J Williams

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The intramolecular Diets-Alder reactions of a series of ether-tethered trienes 3a-3o show varying selectivities according to the nature of the dienophile-activating group and the presence of substituents in the linking chain. Some tether-cleaving reactions are reported.

Original languageEnglish
Pages (from-to)695-724
Number of pages30
JournalTetrahedron
Volume52
Issue number2
Publication statusPublished - 8 Jan 1996

Keywords

  • SILYL ACETAL TRIENES
  • STEREOCHEMICAL ASPECTS
  • LEWIS ACID
  • CYCLOADDITIONS
  • CLEAVAGE
  • STEREOCONTROL
  • ALLYLSILANES
  • CHEMISTRY
  • EFFICIENT
  • STRATEGY

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