Abstract
The intramolecular Diets-Alder reactions of a series of ether-tethered trienes 3a-3o show varying selectivities according to the nature of the dienophile-activating group and the presence of substituents in the linking chain. Some tether-cleaving reactions are reported.
Original language | English |
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Pages (from-to) | 695-724 |
Number of pages | 30 |
Journal | Tetrahedron |
Volume | 52 |
Issue number | 2 |
Publication status | Published - 8 Jan 1996 |
Keywords
- SILYL ACETAL TRIENES
- STEREOCHEMICAL ASPECTS
- LEWIS ACID
- CYCLOADDITIONS
- CLEAVAGE
- STEREOCONTROL
- ALLYLSILANES
- CHEMISTRY
- EFFICIENT
- STRATEGY