INTRAMOLECULAR DIELS-ALDER REACTIONS OF SULFONYL-SUBSTITUTED TRIENES

D CRAIG, D A FISCHER, O KEMAL, A MARSH, T PLESSNER, A M Z SLAWIN, D J WILLIAMS

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The synthesis and thermal intramolecular Diels-Alder reactions of a series of sulphonyl-substituted deca-, undeca- and dodecatrienes have been carried out. The steroselectivities of these reactions are discussed, and methylation reactions of the bicyclic products are described.

Original languageEnglish
Pages (from-to)3095-3128
Number of pages34
JournalTetrahedron
Volume47
Issue number18-19
Publication statusPublished - 6 May 1991

Keywords

  • STEREOSELECTIVE SYNTHESIS
  • STEREOCHEMICAL ASPECTS
  • VINYLIC SULFONES
  • (Z)-1-IODO-1-ALKENES
  • OLEFINATION
  • REAGENTS

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