Interception of a Rh-(I)-Rh-(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)(2){(R,R)-Ph-BPE}]

Delphine Crozet; David McKay; Christian Bijani; Aitor Gual; Cyril Godard; Carmen Claver; Laurent Maron; Martine Urrutigoity; Philippe Kalck

doi:10.1039/c2dt12400a

Interception of a Rh-(I)-Rh-(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)(2){(R,R)-Ph-BPE}]

Delphine Crozet, David McKay, Christian Bijani, Aitor Gual, Cyril Godard, Carmen Claver, Laurent Maron, Martine Urrutigoity^*, Philippe Kalck

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Reaction of [Rh(CO)(2){(R,R)-Ph-BPE}][BF4] 1 under 7 bar H-2 provides the dihydride [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}] [BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph-BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh-(I)-Rh-(III) complex [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF4] 4.

Original language	English
Pages (from-to)	3369-3373
Number of pages	5
Journal	Dalton Transactions
Volume	41
Issue number	12
DOIs	https://doi.org/10.1039/c2dt12400a
Publication status	Published - 2012

Keywords

SELECTIVE HYDROAMINOMETHYLATION
ASYMMETRIC HYDROGENATION
RHODIUM COMPLEX
LIGANDS
IRIDIUM
REACTIVITY
HYDROFORMYLATION
1-HEXENE
H-2

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title = "Interception of a Rh-(I)-Rh-(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)(2){(R,R)-Ph-BPE}]",

abstract = "Reaction of [Rh(CO)(2){(R,R)-Ph-BPE}][BF4] 1 under 7 bar H-2 provides the dihydride [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}] [BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph-BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh-(I)-Rh-(III) complex [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF4] 4.",

keywords = "SELECTIVE HYDROAMINOMETHYLATION, ASYMMETRIC HYDROGENATION, RHODIUM COMPLEX, LIGANDS, IRIDIUM, REACTIVITY, HYDROFORMYLATION, 1-HEXENE, H-2",

author = "Delphine Crozet and David McKay and Christian Bijani and Aitor Gual and Cyril Godard and Carmen Claver and Laurent Maron and Martine Urrutigoity and Philippe Kalck",

year = "2012",

doi = "10.1039/c2dt12400a",

language = "English",

volume = "41",

pages = "3369--3373",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "12",

}

TY - JOUR

T1 - Interception of a Rh-(I)-Rh-(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)(2){(R,R)-Ph-BPE}]

AU - Crozet, Delphine

AU - McKay, David

AU - Bijani, Christian

AU - Gual, Aitor

AU - Godard, Cyril

AU - Claver, Carmen

AU - Maron, Laurent

AU - Urrutigoity, Martine

AU - Kalck, Philippe

PY - 2012

Y1 - 2012

N2 - Reaction of [Rh(CO)(2){(R,R)-Ph-BPE}][BF4] 1 under 7 bar H-2 provides the dihydride [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}] [BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph-BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh-(I)-Rh-(III) complex [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF4] 4.

AB - Reaction of [Rh(CO)(2){(R,R)-Ph-BPE}][BF4] 1 under 7 bar H-2 provides the dihydride [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}] [BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph-BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh-(I)-Rh-(III) complex [Rh(H)(2)(CO)(2){(R,R)-Ph-BPE}][BF4] 4.

KW - SELECTIVE HYDROAMINOMETHYLATION

KW - ASYMMETRIC HYDROGENATION

KW - RHODIUM COMPLEX

KW - LIGANDS

KW - IRIDIUM

KW - REACTIVITY

KW - HYDROFORMYLATION

KW - 1-HEXENE

KW - H-2

U2 - 10.1039/c2dt12400a

DO - 10.1039/c2dt12400a

M3 - Article

SN - 1477-9226

VL - 41

SP - 3369

EP - 3373

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Interception of a Rh-(I)-Rh-(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)(2){(R,R)-Ph-BPE}]

Abstract

Keywords

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