Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

Mantha Tsiouri; Konstantina Skorda; Christos Papadimitriou; Yang Li; J. Derek Woollins; John C. Plakatouras

doi:10.1155/2010/613140

Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

Mantha Tsiouri, Konstantina Skorda, Christos Papadimitriou, Yang Li, J. Derek Woollins, John C. Plakatouras

Research output: Contribution to journal › Article › peer-review

Abstract

The novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.

Original language	English
Article number	613140
Number of pages	7
Journal	Bioinorganic Chemistry and Applications
Volume	2010
DOIs	https://doi.org/10.1155/2010/613140
Publication status	Published - 2010

Keywords

Crystal-structure
Macrocyclic complex
Metal-complexes
Ligands
Europium(III)
Neodymium(III)
Yttrium(III)
Luminescence
Copper(III)
Nickel(II)

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10.1155/2010/613140

TsiourietalBioinorganicChemApp2010Interactions613140
Copyright © 2010 Mantha Tsiouri et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Tsiouri, M., Skorda, K., Papadimitriou, C., Li, Y., Woollins, J. D., & Plakatouras, J. C. (2010). Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine). Bioinorganic Chemistry and Applications, 2010, Article 613140. https://doi.org/10.1155/2010/613140

@article{34a499f02a9c4c05a69b1ac21bcb39ec,

title = "Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)",

abstract = "The novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.",

keywords = "Crystal-structure, Macrocyclic complex, Metal-complexes, Ligands, Europium(III), Neodymium(III), Yttrium(III), Luminescence, Copper(III), Nickel(II)",

author = "Mantha Tsiouri and Konstantina Skorda and Christos Papadimitriou and Yang Li and Woollins, {J. Derek} and Plakatouras, {John C.}",

note = "This research was cofunded by the European Union in the framework of the program “Heraklitos” of the “Operational Program for Education and Initial Vocational Training” of the 3rd Community Support Framework of the Hellenic Ministry of Education, funded by 25% from national sources and by 75% from the European Social Fund (ESF).",

year = "2010",

doi = "10.1155/2010/613140",

language = "English",

volume = "2010",

journal = "Bioinorganic Chemistry and Applications",

issn = "1565-3633",

publisher = "Hindawi Publishing Corporation",

}

Tsiouri, M, Skorda, K, Papadimitriou, C, Li, Y, Woollins, JD & Plakatouras, JC 2010, 'Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)', Bioinorganic Chemistry and Applications, vol. 2010, 613140. https://doi.org/10.1155/2010/613140

Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine). / Tsiouri, Mantha; Skorda, Konstantina; Papadimitriou, Christos et al.
In: Bioinorganic Chemistry and Applications, Vol. 2010, 613140, 2010.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base

T2 - new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

AU - Tsiouri, Mantha

AU - Skorda, Konstantina

AU - Papadimitriou, Christos

AU - Li, Yang

AU - Woollins, J. Derek

AU - Plakatouras, John C.

N1 - This research was cofunded by the European Union in the framework of the program “Heraklitos” of the “Operational Program for Education and Initial Vocational Training” of the 3rd Community Support Framework of the Hellenic Ministry of Education, funded by 25% from national sources and by 75% from the European Social Fund (ESF).

PY - 2010

Y1 - 2010

N2 - The novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.

AB - The novel lanthanide(III) complexes [Ln(NO3)(2)L](NO3)center dot 3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)(3)L](NO3)center dot 2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N'E)-2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 4 was also characterized with crystallographic studies: orthorhombic P2(1)2(1)2(1), a = 10.6683(14), b = 13.4752(15), c = 19.3320(26) angstrom. In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.

KW - Crystal-structure

KW - Macrocyclic complex

KW - Metal-complexes

KW - Ligands

KW - Europium(III)

KW - Neodymium(III)

KW - Yttrium(III)

KW - Luminescence

KW - Copper(III)

KW - Nickel(II)

U2 - 10.1155/2010/613140

DO - 10.1155/2010/613140

M3 - Article

SN - 1565-3633

VL - 2010

JO - Bioinorganic Chemistry and Applications

JF - Bioinorganic Chemistry and Applications

M1 - 613140

ER -

Interactions of trivalent lanthanide cations with a new hexadentate di-Schiff base: new lanthanide(III) complexes from (NE,N ' E)-2,2 '-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)

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Keywords

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